ISSN:
1588-2837
Keywords:
Phenyl salicylate
;
DL-proline
;
cationic micelles
;
kinetics aminolysis and hydrolysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Pseudo-first order rate constants (kobs) obtained for the reaction of ionized phenyl salicylate (PS-) with anionic DL-proline (Prl-) at a constant [NaOH] and [CTABr] (where CTABr represents cetyltrimethylammonium bromide) and 35°C, show a linear increase with increasing total concentration of Prl-; Nucleophilic second-order rate constants (kn obs) for the reactions of Prl- with PS- reveal a nearly 5-fold decrease with the increase in [CTABr] from 0.0 to 0.01 M.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1005644909911
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