ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Cybernetics, Artificial Intelligence and Robotics  (5)
  • ESR spectroscopy  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1891-1898 
    ISSN: 0009-2940
    Keywords: ESR spectroscopy ; Conformational analysis ; Carbohydrate radicals ; Anomeric effect ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Unsubstituted and 2-substituted (fluoro, tosylamino, n-propyl) 3,4,6-tri-O-acetyl-2-deoxypyranosyl radicals are obtained by reaction of the corresponding pyranosyl bromides or phenylselenides with photolytically generated trimethyltin radicals in benzene solution. Analysis of the ESR hyperfine splittings reveals that the 2-deoxy-2-fluoroglucopyranosyl radical exists in a boat-like conformation at room temperature, whereas the others retain the 4C1 chair conformation of the starting material. The observed conformational effects are explained by a “quasi-homo-anomeric” frontier orbital interaction of the nx lone pair of the ring oxygen atom with the σ* MO of the β-C-O bond, in which the singly occupied p orbital at C-1 acts as a mediator for this 1,3-anomeric interaction.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1155-1160 
    ISSN: 0009-2940
    Keywords: Carbohydrate radicals ; Conformational analysis ; ESR spectroscopy ; Anomeric effect ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acetylated 1-cyano- and 1-chloro-pyranos-1-yl radicals and 5-acetoxycarbonyl-, 5-methoxycarbonyl-, and 5-unsubstituted pyranosan-5-yl radicals were generated from the corresponding bromides by bromine abstraction with trimethyltin radicals. The conformation of these radicals, as deduced from the ESR hyperfine splittings, is explained by the combined action of a quasi-anomeric and a homo-anomeric stabilization effect. A captodative substitution pattern of the radical center does not influence the conformations.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0009-2940
    Keywords: Free radicals ; Rearrangement ; ESR spectroscopy ; Adamantane matrix ; Molecular orbital calculations ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The ESR spectra observed after X-irradiation of bicyclo-[5.1.0]octa-2,5-diene (homotropylidene) (12) in a [D16]adamantane matrix at 210 K have been identified to be mainly due to the cyclooctatrienyl radical (8), formed by thermal ring opening of the initial bicyclo[5.1.0]octa-2,5-diene-4-yl (homotropylidenyl) radical (7). The same spectrum has also been observed in X-irradiation of bromocyclooctatriene and a mixture of bromocyclooctatriene and 7-bromobicyclo[4.2.0]cycloocta-2,4-diene in a [D16]adamantane matrix. In all cases, UV irradiation of the matrix caused an irreversible transformation of radical 8 (and probably 7) into the bicyclo[3.3.0]octa-2,6-diene-4-yl radical (17). Tricyclo[3.3.0.02,4]oct-6-en-7-yl radical (19), generated by X-irradiation of tricyclo[3.3.0.02,4]oct-2-ene (20) in adamantane, is thermally stable up to 370 K, but also undergoes a facile rearrangement to the radical 17 on UV irradiation. This process is reasonably explained to occur stepwise via radicals 7 and 8. The postulated reaction paths and the spectral assignments are supported by semiempirical (AM1, PM3), abinitio (UHF/3-21G*), and molecular mechanics (MM2ERW) calculations, which are in accord with the finding that 8 is energetically more stable than 7. The quantum mechanical calculations predict that a degenerate sigmatropic circumambulation of the cyclopropane ring in radical 7 should favorably compete with its ring opening.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2018-06-11
    Description: For most of the history of space exploration, human and robotic programs have been independent, and have responded to distinct requirements. The NASA Vision for Space Exploration calls for the return of humans to the Moon, and the eventual human exploration of Mars; the complexity of this range of missions will require an unprecedented use of automation and robotics in support of human crews. The challenges of human Mars missions, including roundtrip communications time delays of 6 to 40 minutes, interplanetary transit times of many months, and the need to manage lifecycle costs, will require the evolution of a new mission operations paradigm far less dependent on real-time monitoring and response by an Earthbound operations team. Robotic systems and automation will augment human capability, increase human safety by providing means to perform many tasks without requiring immediate human presence, and enable the transfer of traditional mission control tasks from the ground to crews. Developing and validating the new paradigm and its associated infrastructure may place requirements on operations design for nearer-term lunar missions. The authors, representing both the human and robotic mission operations communities, assess human lunar and Mars mission challenges, and consider how human-robot operations may be integrated to enable efficient joint operations, with the eventual emergence of a unified exploration operations culture.
    Keywords: Cybernetics, Artificial Intelligence and Robotics
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2019-08-26
    Description: For most of the history of space exploration, human and robotic programs have been independent, and have responded to distinct requirements. The NASA Vision for Space Exploration calls for the return of humans to the Moon, and the eventual human exploration of Mars; the complexity of this range of missions will require an unprecedented use of automation and robotics in support of human crews. The challenges of human Mars missions, including roundtrip communications time delays of 6 to 40 minutes, interplanetary transit times of many months, and the need to manage lifecycle costs, will require the evolution of a new mission operations paradigm far less dependent on real-time monitoring and response by an Earthbound operations team. Robotic systems and automation will augment human capability, increase human safety by providing means to perform many tasks without requiring immediate human presence, and enable the transfer of traditional mission control tasks from the ground to crews. Developing and validating the new paradigm and its associated infrastructure may place requirements on operations design for nearer-term lunar missions. The authors, representing both the human and robotic mission operations communities, assess human lunar and Mars mission challenges, and consider how human-robot operations may be integrated to enable efficient joint operations, with the eventual emergence of a unified exploration operations culture.
    Keywords: Cybernetics, Artificial Intelligence and Robotics
    Type: 2007 IEEE Aerospace Conference; Mar 03, 2007 - Mar 10, 2007; Big Sky, MT; United States
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2019-07-13
    Description: No abstract available
    Keywords: Cybernetics, Artificial Intelligence and Robotics
    Type: JSC-CN-39290-2 , 2017 Annual Technical Symposium: AIAA Houston-Human Systems Integration ERG Technical Symposium; May 05, 2017; Houston, TX; United States
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2019-07-19
    Description: The United States space policy is evolving toward missions beyond low Earth orbit. In an effort to meet that policy, NASA has recognized Autonomous Mission Operations (AMO) as a valuable capability. Identified within AMO capabilities is the potential for autonomous planning and replanning during human spaceflight operations. That is allowing crew members to collectively or individually participate in the development of their own schedules. Currently, dedicated mission operations planners collaborate with international partners to create daily plans for astronauts aboard the International Space Station (ISS), taking into account mission requirements, ground rules, and various vehicle and payload constraints. In future deep space operations the crew will require more independence from ground support due to communication transmission delays. Furthermore, crew members who are provided with the capability to schedule their own activities are able to leverage direct experience operating in the space environment, and possibly maximize their efficiency. CAST (Crew Autonomous Scheduling Test) is an ISS investigation designed to analyze three important hypotheses about crew autonomous scheduling. First, given appropriate inputs, the crew is able to create and execute a plan in a reasonable period of time without impacts to mission success. Second, the proximity of the planner, in this case the crew, to the planned operations increases their operational efficiency. Third, crew members are more satisfied when given a role in plan development. This presentation shows the progress done in this study with a single astronaut test subject participating in five CAST sessions. CAST is a technology demonstration payload sponsored by the ISS Research Science and Technology Office, and performed by experts in Mission Operations Planning from the Flight Operations Directorate at NASA Johnson Space Center, and researchers across multiple NASA centers.
    Keywords: Cybernetics, Artificial Intelligence and Robotics
    Type: JSC-CN-39290-1 , 2017 Annual Technical Symposium: AIAA Houston-Human Systems Integration ERG Technical Symposium; May 05, 2017; Houston, TX; United States
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2019-07-19
    Description: The United States space policy is evolving toward missions beyond low Earth orbit. In an effort to meet that policy, NASA has recognized Autonomous Mission Operations (AMO) as a valuable capability. Identified within AMO capabilities is the potential for autonomous planning and replanning during human spaceflight operations. That is allowing crew members to collectively or individually participate in the development of their own schedules. Currently, dedicated mission operations planners collaborate with international partners to create daily plans for astronauts aboard the International Space Station (ISS), taking into account mission requirements, ground rules, and various vehicle and payload constraints. In future deep space operations the crew will require more independence from ground support due to communication transmission delays. Furthermore, crew members who are provided with the capability to schedule their own activities are able to leverage direct experience operating in the space environment, and possibly maximize their efficiency. CAST (Crew Autonomous Scheduling Test) is an ISS investigation designed to analyze three important hypotheses about crew autonomous scheduling. First, given appropriate inputs, the crew is able to create and execute a plan in a reasonable period of time without impacts to mission success. Second, the proximity of the planner, in this case the crew, to the planned operations increases their operational efficiency. Third, crew members are more satisfied when given a role in plan development. This paper presents the results from a single astronaut test subject who participated in five CAST sessions. The details on the operational philosophy of CAST are discussed, including the approach to crew training, selection criteria for test days, and data collection methods. CAST is a technology demonstration payload sponsored by the ISS Research Science and Technology Office, and performed by experts in Mission Operations Planning from the Flight Operations Directorate at NASA Johnson Space Center, and researchers across multiple NASA centers. It is hoped the results of this investigation will guide NASA's implementation of autonomous mission operations for long duration human space missions to Mars and beyond.
    Keywords: Cybernetics, Artificial Intelligence and Robotics
    Type: JSC-CN-38934 , International Astronautical Congress 2017 (A Joint Session of the Human Spaceflight and Space Operations Symposia); Sep 25, 2017 - Sep 29, 2017; Adelaide; Australia
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...