ISSN:
1435-1528
Keywords:
Key words Spurt
;
oscillations
;
wall slip
;
capillary flows
;
stick-slip
;
critical shear stress
;
loss of fluidity
;
hardening
;
parameter
;
extrudate distortion
;
melt fracture
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Abstract The paper presents an approach for modeling polymer flows with non-slip, slip and changing non-slip – slip boundary conditions at the wall. The model consists of a viscoelastic constitutive equation for polymer flows in the bulk, prediction of the transition from non-slip to sliding boundary conditions, a wall slip model, and a model for the compressibility effects in capillary polymer flows. The bulk viscoelastic constitutive equation contains a hardening parameter which is solely determined by the polymer molecular characteristics. It delimits the conditions for the onset of solid, rubber-like behavior. The non-monotone wall slip model introduced for polymer melts, modifies a slip model derived from a simple stochastic model of interface molecular dynamics for cross-linked elastomers. The predictions for the onset of spurt, as well as the numerical simulations of hysteresis, spurt, and stress oscillations are demonstrated. They are also compared with available data for a high molecular weight, narrow distributed polyisoprene. By using this model beyond the critical conditions, many of the qualitative features of the spurt and oscillations observed in capillary and Couette flows of molten polymers, are described.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00366817
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