ISSN:
1435-1528
Keywords:
Composite
;
silane coupling agent
;
interface
;
Fourier transform infraredspectroscopy
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Abstract Model composites of spherical glass particles dispersed in a matrix of high density polyethylene were prepared both with and without interfacial modification by an azidofunctional trialkoxysilane. Dynamic mechanical measurements of the composites in the melt state were recorded. The unmodified composites behave as theoretically predicted and the effect of particle—particle interaction at high volume fractions can be measured. The composites with a modified interfacial region have greater shear moduli due to the effect of a region surrounding the particle modified by the silane. The material in this region is largely bound to the glass surface and was examined by Fourier transform infrared spectroscopy after extraction of the bulk matrix. Theoretical calculations are shown to be useful in calculating the mechanical properties and volume fraction of the interfacial region.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01332160
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