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  • 1
    Electronic Resource
    Electronic Resource
    Zum Chlor/Brom-Austausch an Disilanen (1984)
    Springer
    Monatshefte für Chemie 115 (1984), S. 1125-1132 
    Details
    ISSN: 1434-4475
    Keywords: Disilane ; Redistribution reaction ; Cl/Br-Exchange
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Redistribution reactions between a mixture of Si2 Me 2Cl4 and Si2 Me 2Br4 show an exchange of halogen atoms at room temperature. After 10 hours at 60 °C the equilibrium state is attained and all possible compounds Si2 Me 2Cl4−n Br n are formed, but not in a statistical distribution. Possible reasons for this distribution and general rules for the exchange of substituents on disilanes are postulated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00809343
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