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  • Circulardichroism  (1)
  • multilayer formation
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  • 1
    ISSN: 1435-1536
    Schlagwort(e): Circulardichroism ; gelatin ; nonionicsurfactants
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract Using CD-measurements the influence of nonionic surfactants (dodecyl polyoxyethylene, ethoxylated para tert. octyl phenol, commercial nonionic WON 100 and octyl diethyl phosphinoxid) on the secondary structure of gelatin in aqueous solutions was investigated. At surfactant concentrations smaller than the c.m.c. the triple helical content of the gelatin is increased. At concentrations exceeding the c.m.c. the triple helical content decreases. Chain reversals of the peptide chains after the destruction of the triple helical structure were shown to appear in acidic environment at 298 K. This destruction is reversible by rechilling the solution.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 262 (1984), S. 821-826 
    ISSN: 1435-1536
    Schlagwort(e): Surface rheology ; adsorbed gelatin layers ; surface tension ; multilayer formation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract Adsorbed gelatin layers have been characterized by measuring the surface equilibrium tension and surface rheological parameters of shear, found by surface creep experiments. After the determination of these parameters the solution below the adsorption layer (gelatin + phosphate buffer) was substituted by a gelatin-free phosphate-buffer-solution. The differences of the parameters calculated before and after the substitution of the bulk phase allowed us to prove some model assumptions of the protein adsorption and to characterize the physical contents of some of the surface rheological parameters determined. The parameters calculated and measured permit the distinction of three different concentration ranges of gelatin: 1) the range of reversible adsorption layer. 2) the ranges of saturated, irreversible adsorption layer, and 3) the range of multilayer formation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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