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  • 1
    Electronic Resource
    Electronic Resource
    Metallkomplexe mit biologisch wichtigen Lisganden, LXXXIPart LXXX: Ref.. Synthese und Kristallstruktur von Rh(I)-Komplexen mit α-Aminocarboxylat-Liganden (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 1127-1130 
    Details
    ISSN: 0009-2940
    Keywords: Rhodium(I) ; α-Aminocarboxylate ; Crystal structure ; Hydrogen bonding ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Metal Complexes Containing Biologically Important Ligands, LXXXPart LXXX: Ref. .  -  Synthesis and Crystal Structure of Rhodium(I) Chelates with α-Amino Carboxylates Part LXXX: Ref.The α-amino carboxylate complexes were prepared from Rh(Cl)(CO)(PPh3)2 and H2NC(H)(R)CO2 in the presence of AgBF4 and characterized by X-ray diffraction. In the crystal the complexes form chains by hydrogen bridges between amino and carboxylate groups of adjacent molecules.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951281111
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  • 2
    Electronic Resource
    Electronic Resource
    Heterobimetallic and Mixed-Valence Chloro-Bridged Complexes with Orthometalated Rhodium(III) and Iridium(III) Fragments (1998)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1187-1192 
    Details
    ISSN: 1434-1948
    Keywords: Iridium ; Rhodium ; Chloro-bridged complexes ; Heterobimetallic complexes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis and characterization of heterobimetallic and mixed-valence complexes in which orthometalated [(ppy)2MCl] (M = Rh, Ir; ppy = 2-phenylpyridine anion) and [(bzq)2RhCl] (bzq = benzo[h]quinoline anion) fragments are linked via chloro-bridges with rhodium(I), iridium(I), palladium(II), and platinum(II) fragments is reported. These complexes are formed in nearly quantitative yields by metathesis reactions from the respective homodimeric compounds. The structures of [(ppy)2Rh(μ-Cl)2Rh(cod)] (cod = η4-1,5-cyclooctadiene) and [(ppy)2Rh(μ-Cl)2Pt(PBu3)-Cl] were determined by X-ray structure analyses.
    Type of Medium: Electronic Resource
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