ISSN:
0009-2940
Keywords:
Cyclopentadienes, bicyclic
;
Face selectivity
;
endo selectivity
;
Chiral discrimination
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A general synthetic route to the enantiopure bicyclic cyclopentadienes (S)-3 and (R)-3 of the hydrindane series, starting from the Hajos-Wiechert ketone 4 or its enantiomer is described. Reasons for the excellent face and endo selectivity of cycloadditions and the resulting consequences for chiral recognition are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941271223
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