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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 20 (1997), S. 275-283 
    ISSN: 0935-6304
    Keywords: Purge-and-Trap ; GC-FTIR GC-MS ; Aroma Strawberries ; Fragaria anannassa ; Principal components ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The aroma composition of three different Fragaria anannassa cul-tivars Selva, Chandler, and Osso Grande) is studied by purge-and-trap HRGC and the components identified by MRGC-MS and HRGC-FTIR. The chromatographic aroma profiles from four different maturation stages in each variety are compared and the similarities accessed by principal component analysis (PCA). The contents in n-hexanal and hex-2(Z)-enal are characteristic features of the green stage in the three varieties where the content differences in methyl, ethyl, and butyl acetates act as typifying variables among varieties. Ethyl acetate acts as an important differentiation variable for the Selva variety. In the mature stage, the three cultivars may be distinguished from each other through their relative contents of methyl and ethyl 2-methylbutyrate (Selva), methyl 2-methyl-butyrate, methyl butyrate (Chandler), methyl and ethyl butyrates, and methyl caproate (Osso Grande).
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 19 (1996), S. 161-164 
    ISSN: 0935-6304
    Keywords: L-2-Hydroxyglutaric acid ; L-2-Hydroxyglutaric aciduria ; Chiral HRGC ; Chiral liquid phases ; Cyclodextrins ; 1(R)-trans-N-N'-1,2-cyclohexenylbisbenzamideoligosiloxane ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: L-2-Hydroxyglutaric aciduria is a recently discovered inherited neurometabolic disease for which diagnostic identification of the right enantiomer is required. A method is described where alkyl esters of both L-and D-2-hydroxyglutaric acids are prepared without side lactonization. Esterification is achieved at room temperature by reaction with appropriate alkyl chloroformates. This method avoids lactonization, in contrast to esterification with alcohols in acidic media or with diazomethane. The identity of the derivatives is established by HRGC-FTIR and HRGC-MS. Chiral HRGC separation with capillaries coated with 1(R)-trans-N-N'-1,2-cyclohexylenebisbenzamideoligodimethyL-siloxane and with a cyclodextrin is compared. The method is adequate for quantitative determinations.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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