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  • Chevron-notch method.  (1)
  • channel blockers  (1)
  • surface basicity  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 31 (1992), S. 1609-1612 
    ISSN: 0031-9422
    Keywords: Apocynaceae ; Catharanthus roseus ; aminophenylpyridine ; biotransformation. ; channel blockers ; nifedipine ; nitrophenylpyridine: nitrosophenylpyridine
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-879X
    Keywords: aluminophosphate oxynitrides (AlPON) ; surface basicity ; CO2 adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Aluminophosphate oxynitrides (AlPON) are new catalysts obtained by nitridation of AlPO4 showing a high surface area and an enhanced surface basicity. In this article, surface basicity is evaluated by CO2 adsorption and related to the nitrogen content. CO2 simultaneously adsorbs linearly and as bidentate carbonate and bicarbonate species on AlPON surface. Particularly strong basic centers involving hydroxyls linked to Al cations and in the vicinity of terminal –PNH2 groups are identified. However, the influence of nitrogen content on surface basicity of AlPON is mostly through the change in the number of sites rather than on the modification of their strength. Activity results obtained for AlPON in base-catalyzed reactions are related with their capability of adsorbing CO2.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of fracture 91 (1998), S. 83-101 
    ISSN: 1573-2673
    Keywords: Paticulate composites ; cxynitride glasses ; fracture toughness ; Chevron-notch method.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture toughness K1c and the effective fracture surface energy γeff, of oxynitride glass (m)/SiC(p) brittle particulate composites were measured by means of stable fracture tests, using chevron-notch three-point bend specimens. In comparison to oxide glasses, the oxynitride glass matrix is noticeably tougher: K1cm = 1.2 MPa. $$\sqrt m$$ and γeff = 5 J/m2. The addition of SiC particles, 6 μm in diameter, results in a significant toughening: K1c = 2.5 MPa. $$\sqrt m$$ and γeff = 9.1 J/m2 for the composite with 40 vol\% SiC. In such systems, with strong particle-matrix interfacial bonding, and where (Ep, K1cp, σrp) 〉 (Em, K1cm, σrm), the main toughening contribution is due to a discrete pinning of the crack by particles near the crack tip in conjunction to bowing of the crack front between particles, and to a small scale bridging mechanism.
    Type of Medium: Electronic Resource
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