ISSN:
0268-2605
Keywords:
carbohydrate-modified phenylsiloxane
;
surfactants
;
wetting behaviour
;
superspreading
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The dynamic wetting behaviour on a perfluorinated, low-energy solid has been investigated for a carbohydrate-modified phenylsiloxane surfactant. The surfactant concentration, the rate of interface generation and the [solid/liquid interface area] : [liquid/vapour interface area] ratio were varied systematically. Dynamic data for the liquid/vapour (γlv) and solid/liquid (γsl) interfacial tension as well as their Lifshitz-van der Waals and donor-acceptor contributions were determined under strictly controlled conditions. Since γsl reacts sensitively to variations of the surfactant concentration and the rate of interface generation, the covering of the liquid/non-polar solid interface is assumed to be a spreading limiting factor. The corresponding γlv values remain constant and close to those obtained under equilibrium conditions. Copyright © 1998 John Wiley & Sons, Ltd.
Additional Material:
11 Ill.
Type of Medium:
Electronic Resource
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