ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Sorting

Electronic Resource

α-Alkyl-α-aminosilanes: Synthesis via Alkylation and Hydrosilylation (1997)

Sieburth, Scott McN. ; Somers, Joseph J. ; O'Hare, Heather K. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Applied Organometallic Chemistry 11 (1997), S. 337-343

add to mindlist on the mindlist

Details

ISSN: 0268-2605

Keywords: organosilane ; α-alkyl-α-aminosilane ; metalation ; hydrosilylation ; rearrangement ; Brook ; Chemistry ; Industrial Chemistry and Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The readily available aminomethylsilanes can be utilized to prepare the less available α-alkyl-α-aminosilanes. Versatile t-butoxy-carbonal (Boc) derivatives can be metalated between nitrogen and silicon, and then alkylated by an electrophile at this position. Two alternative procedures were also developed, including an aza-reverse-Brook rearrangement of metalated N-silylcarbamates and hydrosilylation of N-alkenylcarbamates. © 1997 by John Wiley & Sons, Ltd.

Additional Material: 18 Ill.

Type of Medium: Electronic Resource

Permalink

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

hit 1 - 1 | 1 hit