ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Tetra-n-butylammonium peroxydisulfate (Bu4N+ -OS(O2)O-O(O2)SO- +NBu4: (TBA)2S2O8) has been successfully prepared and turned out to be a useful source of the tetra-n-butylammonium sulfate radical in organic solvents. Primary, secondary, and tertiary alcohols containing functional groups, such as benzylic, allylic, and sulfide, reacted with tetrahydrofuran or tetrahydropyran in the presence of (TBA)2S2O8 to give the corresponding 2-tetrahydrofuranyl- or 2-tetrahydropyranyl-ether in excellent yields under nearly neutral conditions.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520060410
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