Electronic Resource
Weinheim
:
Wiley-Blackwell
Angewandte Chemie International Edition in English
7 (1968), S. 754-765
ISSN:
0570-0833
Keywords:
Electron-rich alkenes
;
Tetraaminoethylen
;
Alkenes
;
Tetramethoxyethylene
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Olefins are normally preferentially attacked by electrophiles. This trend is strengthened in enol ethers and enamines, and is particularly pronounced in tetramethoxyethylene and in tetraaminoethylenes. These electron-rich olefins are accordingly also excellent reducing agents. In their reactivity, therefore, they behave as counterparts of tetracyanoethylene. This compound shares with the electron-rich olefins a strong tendency to undergo cycloadditions, the electron-rich olefins adding particularly readily to electrophiles.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196807541
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