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  • Chemistry  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 497-501 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymer modification by addition of reinforcing agents represents a popular means of increasing physical property values. The polymer matrix has been forced to accept up to 55 percent by weight of fibrous reinforcement and 80 percent by weight of powdered types in order to meet application requirements. These materials demand sophisticated mixing equipment which must provide extensive intake and conveying capabilities, polymer wetting of reinforcement, and dispersion of reinforcement. This process must also be conducted with controlled shear intensity and excellent temperature and residence time control in order to respect polymer thermal sensitivity and product requirements. The extrusion process is a proven economical method for incorporating reinforcements into polymer resins. Co-rotating intermeshing twin-screw extruders are particularly suited for these tasks. Positive conveying, self-wiping, and shear intensive mixing characteristics provided by the screw mechanism satisfy requirements of reinforcement compounding. This mechanism allows interruption of streamline flow which is needed to disperse both high and low aspect ratio reinforcing agents into a polymer matrix. Mathematical representation of the benefits of twin-screw extrusion (relative to single-screw) related to pumping and mixing capability have been developed based on the classical pressure flow continuity equation with proper selection of boundary conditions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1040-0397
    Keywords: Photo-cured membrane ; Calcium ion-selective electrode ; Perchlorate tolerance ; Flow injection potentiometry ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An improved photo-cured membrane selective to calcium was developed based on the calcium bis[4-(l, 1,3,3-tetramethylbutyl)phenyl] phosphate ionophore and incorporates the lipophilic additive, potassium tetrakis(p-chloropheny1)borate. The calcium electrode exhibited a hyper-Nernstian response of 31.0 mV change per activity decade and a log-linear range between 1 × 10-5 to 0.1 M in pure calcium chloride solution, in steady-state mode. The calcium electrode was fast responding, reaching 90% of steady-state value in 5s making it ideal for flow injection measurements. The photo-cured electrode can measure calcium in a high perchlorate background, and was used to determine the total calcium level in full cream milk that was digested by a nitric/perchloric acid mixture. The results obtained were in good agreement with atomic absorption spectroscopy measurements.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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