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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 20 (1978), S. 1577-1594 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By means of stimulus-response experiments with a Li+ tracer, a description of the fluid flow in a 30 m3 reactor, used for anaerobic treatment of wastewater, was derived. It appeared that of the three parts that could be distinguished in the reactor (the sludge bed. The sludge blanket, and the settler), the sludge bed could be described as a combination of two perfectly mixed regions with bypassing and return flows; the sludge blanket was perfectly mixed, while the fluid flow in the settler could be described as plug flow. From experiments performed under different conditions it was concluded that 60 m3 gas/day were sufficient to provide good mixing and also that the height of the sludge bed should be 2-3 m. From this last conclusion it follows, e.g., that scale-up of the 30 m3 reactor should be done by increasing the cross section of the reactor while homogeneously distributing the influent over the bottom.
    Additional Material: 14 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 24 (1982), S. 1975-1989 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model has been developed and experimentally checked for the physical behavior of sludge in the blanket in upflow reactors. The model is based on the mass balance for the sludge in the blanket, and can be used to predict the distribution of sludge in an upflow reactor in relation with the gas production, sludge settling characteristics, and the linear fluid velocity in the reactor. The quantitative values of the transport factors that are a measure of the efficiency of the transport of sludge by the fluid streams occurring in the reactor were determined experimentally in reactors of 30- and 200-m3 volumes. As this was done for wastewater containing lower fatty acids as the main organic pollutants and for sludge with good settling characteristics, the predictive value of the model is limited. It may be used for the second (methane forming) step of anaerobic treatment of wastewater.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 25 (1983), S. 2531-2556 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A quantitative description has been presented of anaerobic treatment in an upflow reactor of dilute wastewater containing lower fatty acids as the main pollutant. It contains as its principal elements mathematical descriptions of the dynamic behavior and the distribution of both the fluid and the anaerobic sludge in the reactor, and a quantification of the kinetics of the anaerobic conversion of the organic waste and of the formation of bacterial products and methane. These elements have been taken together in mass (organic carbon) balances for the substrate, the methane, and the bacterial products, over the two most important reactor parts: the sludge bed and the sludge blanket. In the second part of this article, the description has been used for prediction and determination of the optimum reactor dimensions and process conditions. These optimum values can be used for the design of new reactors and for the establishment of the best suited process operation, which is important for obtaining the best purification results and process reliability at minimum investment and operation costs.
    Additional Material: 11 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 24 (1982), S. 443-459 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Residence-time-distribution experiments for the fluid in a 30-m3 pilot plant and a 200-m3 prototype upflow reactor were performed by means of continuous injection of an LiCl solution as a tracer in the influent of the reactor and measurement of the response of this stimulus on several location in the reactor and in the effluent. In a similar way as described in an article published earlier, models have been developed by use of the measured data of the fluid flow pattern which consisted of region of ideal mixing, plug flow, dead space, and short circuiting. It appeared that the fluid flow patterns in the two reactors were to a large extent analogous. For the pilot plant, three-mixer models appeared to be appropriate while for the prototype reactor two-mixer models have been found. This differences was a result of the difference in the heights of the sludge beds in the reactors: 2-3 m in the pilot plant and only 0.4 m in the prototype reactor, a result of too small an amount of sludge. Another differences was that, due to large amount of mud in the prototype reactor, a region of dead space occurred in the models for the fluid flow pattern in this reactor. The dimension of the prototype reactor have been chosen according to several recommendations obtained from work with the pilot plant (e.g., scale-up should be done by increasing the cross section of the reactor; one influent point should be applied per 5 m2 bottom surface). The results presented here clearly show the value of these recommendations.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 18 (1979), S. 1533-1542 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An expression is derived for the field correlation function of the light scattered from a solution of lollipop-shaped particles. Such particles are a tractable model of certain bacteriophages. They are assumed to consist of an ellipsoidal head containing optically anisotropic scattering material and a tail which does not scatter. Because of the tail, Brownian rotational movement occurs around a center of rotational friction which is at a distance r0 from the center of the head. The dependence of the field correlation function C(τ) on the rotational diffusion coefficient DR is given by the factor ΣlBl exp[-l(l + 1)DRτ]. It is shown that the tail causes the coefficients Bl to be different from zero for all values of l. Therefore, C(τ) contains a term proportional to exp(-2DRτ), which is not present when r0 = 0. We give plots of Bl for various combinations of parameters. It turns out that dynamic light scattering may be used to measure r0.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 56 (1976), S. 27-36 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Zusammensetzung von Copolymeren aus Vinylacetat (VAc) und Vinylbutyrat (VB) kann schnell und mit genügender Genauigkeit mittels dynamischer thermogravimetrischer Analyse (TGA) festgestellt werden, obgleich Essigsäure und Buttersäure zu gleicher Zeit und unvollständig aus den diesbezüglichen Segmenten abgespalten werden. Die TGA-Resultate werden mit aus gaschromatographischen Analysen erzielten Ergebnissen verglichen; sie liegen innerhalb der experimentellen Fehler. Die Ausweitung auf andere binäre Vinylester-Kombinationen ist wahrscheinlich möglich.
    Notes: The composition of copolymers of vinylacetate (VAc) and vinylbutyrate (VB) can be determined rapidly and satisfactorily by dynamic thermogravimetric analysis (TGA), in spite of the fact that both acetic and butyric acid are abstracted simultaneously and incompletely from their respective segments. The TGA results are compared with those obtained by gaschromatographic analysis of the reaction mixtures during copolymerization, and are within experimental error. Extension of this analysis method to other binary vinylester combinations seems to be possible.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 9 (1977), S. 281-284 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 13C chemical shifts of the diazanaphthalenes have been recorded as a function of the pH value, providing classical titration curves. From these curves the pK1 and pK2 values have been determined taking into account the activity coefficients. The changes in 13C chemical shift under the influence of nitrogen protonation (Δδ) can be described by two protonation parameter sets.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 8 (1976), S. 187-191 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The pH dependence of the 13C chemical shifts (δ) of the diazanaphthalenes has been recorded. From this dependence the pKa values have been determined using the Henderson-Hasselbach equation. The change in 13C chemical shifts under the influence of nitrogen protonation (Δδ) has been predicted using the Δδ values of quinoline and isoquinoline. The correlation between observed and expected Δδ values of the symmetric diazanaphthalenes is very good. Assuming these changes in chemical shifts to be of general validity, the site of protonation in the asymmetric diazanaphthalenes has been determined by comparison of the expected Δδ values for α- and β-nitrogen protonation with the observed ones. The site of protonation for 1,6- and 1,7-naphthyridine is the β-nitrogen atom, whereas for cinnoline both monoprotonated species are present in a significant amount.
    Additional Material: 8 Ill.
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  • 9
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The inhibitor and initiator action of 33 compounds on the bulk polymerization of pure isoprene has been studied. Picric acid was found to be the most powerful inhibitor at 100°C. The conclusion reached in Part I, that the initiator activity of diazoaminobenzene is superior to all other compounds has been found to be valid also between 100-150°C. The heat polymerization of isoprene between 100-150°C. in the presence of picric acid leads only to the formation of dimers. Three of the four possible isomers have been separated. The solid complex compound of diprene (I) with silver nitrate has been used to separate it from dipentene (II) and the hydrocarbon of Lebedew (III, IV) has been identified as a monochloride. The relative yields (I): (II): (III+IV) = 16:1:2 are in agreement with the relative availability and localization of π-electrons in isoprene. Observations on the properties of polyisoprene are in agreement with the more extensive work by d'Ianni. Some remarks on polymers from bulk polymerization are added. Isoprene acts as a powerful inhibitor on the polymerization of vinylidene chloride. This effect is independent of the method of polymerization.
    Additional Material: 4 Ill.
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