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    Electronic Resource
    Electronic Resource
    On the Reaction of Chloroglyoximes with Aryl Isocyanates (1990)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 332 (1990), S. 731-736 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of chloroglyoxime 1 with aryl isocyanates yielded monocarbamates 3, and chlorooxime functional group was unchanged. The 1,3-cycloaddition of nitrile N-oxides generated from 3 to methyl methacrylate gave isoxazole derivatives 5. Compounds 5 were also obtained by carbamoylation of 3-formyl-4-hydro-5-methyl-5-methoxycarbonylisoxazole oxime 6.The selectivity of chloroglyoxime carbamoylation and the poor reactivity of chlorooxime group is general. Examples, involving another oximes and their halogeno derivatives are given.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19903320523
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