ISSN:
0930-7516
Schlagwort(e):
Chemistry
;
Industrial Chemistry and Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
Computer-aided design of a packed column to remove ethanol from aqueous solution with dibutyl butylphosphonate (DBBP) was accomplished with a programme based on the Pratt method and on the slip velocity equation. Reliable data for successful computation were obtained from literature correlations (drop size, hold-up and axial mixing coefficients for different types of packing) and from experimental work (equilibria and kinetics). Equilibrium studies on the H2O-ethanol-dibutyl butylphosphonate system were performed at different temperatures. A decrease in temperature increased the selectivity of the extractant while the distribution coefficient of ethanol, KD ≈ 1.0, remained constant. The behaviour of the system kinetics towards temperature is assessed in order to determine the initial mass transfer flux (892 × 10-3 kg m-2s-1, 30°C) and the activation energy, 22.9 kJ/kmol. The process is governed by the diffusion of the species involved. The influence of the type of packing of the column on its design is analyzed from the inventory volume of the solvent, the total volume of the column and the axial dispersion coefficients under normalised inlet and outlet conditions.
Zusätzliches Material:
6 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/ceat.270170609
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