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  • Artikel  (13)
  • Chemistry  (13)
  • Technik allgemein  (7)
  • Informatik  (6)
  • 1
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: The concept of surface-active comonomers of higher functionality is propsed as a means of increasing reliability of the bonding between preventive and restorative dental materials and tooth structures.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 14 (1980), S. 83-90 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Distributions of Ca-to-Ca distances have been obtained from the crystal structure of hydroxyapatite for all biologically significant planes. Most frequently, calcium ions are separated by about 4, 6.3, 7.9, and 9.0 to 9.6 Å. Frequent occurrence of distances at 10.4, 11.8, and 12.6 Å result from a Ca ion in one repeating unit being paired with a Ca in another unit cell.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 253-265 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Radiopaque glass-resin composites were made for evaluation as denture base materials. The addition of silane-treated, radiopaque, powdered glass to clear poly(methyl methacrylate) resulted in composites that had greater optical translucency than commercially available pink denture base resins. These formulations could be pigmented and opacified to produce materials that simulated oral soft tissues in color and translucency.Other composites were made using various monomer, polymer and glass combinations. Those made from mixes of BIS-GMA, methyl methacrylate, poly(methyl methacrylate), and radiopaque glass had excellent translucency but handling characteristics were less than ideal.Removal of very small glass particles (less than a few μm) appeared to improve optical translucency.A radiographic survey of 12 specimens that contained from 29 to 57% of the radiopaque glass, indicated that all had sufficient radiopacity to aid in localization of swallowed or aspirated dentures made from such materials.Finishing procedures on composite specimens were more difficult and timeconsuming and did not produce surfaces as smooth as those obtained on poly(methyl methacrylate). The finished surfaces felt smooth to the tongue but might stain more easily in the mouth.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 359-371 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Technic dentures were made using composite base materials containing 30,40, and 50 weight % of a silance-treated, readiopaque, powdered glass as the reinforcing filler and poly (methyl methacrylate) as the matrix. Dentures containing no glass were included for comparison. Molar-to-molar dimensional changes, effects of silance treatment fo the procelain teeth and handling and finishing characteristics were determined.Dentures containing glass had less dimensional change during curing and subsequent water storage than those without glass. Thick upper dentrues exhibited the least change and thin lowers, the most. The Differences in the magnitudes of the changes would not be clinically noticeable.Silance treatment fo the procelain teeth in thick upper dentures resulted in breakage of theposterior teeth in almost all instances. posterior teeth also freactured in thick upper dentures containing 40 and 50% of the silance-treated glass even though the teeth were not treatedwith silance.Mixing and molding properties of the composite materials, while acceptabgle, were slightly inferior to thematerial containing ono glass. Finiching characteristics were definitelyinferior in that it was more difficult and time-consuming to attain the fial surfaces and these surfaces were not as smooth as smooth as those in dentures without glass.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 12 (1978), S. 505-515 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Initial rates of ion-exchange adsorption of nickelous or cupric ions with calcium ions on the surface of synthetic hydroxyapatite were studied in aqueous nitrate solutions. A kinetic interpretation has been proposed. The determination of the initial rates is important for a systematic investigation of adhesion of certain properly designe substances that may mediate a chemical bonding between dental resins and “moralanted” calcified tissues.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 245-252 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: The need for esthetic and functionally acceptable radiopaque denture base materials is reflected by numerous reports of patients who ingested or aspirated portions of dentures and reports of difficulties encountered in the removal of these dentures because they could not be located radiographically.The type of denture most commonly ingested or aspirated is a maxillary partial consisting of a palatal piece to which is attached one or more anterior teeth. It may or may not have clasps. Ingestion or aspiration of the foreign body commonly occurs when either broken or ill-fitting dentures are being worn. Few cases have been reported where patients swallowed portions of complete dentures.Previous attempts at providing radiopacity have included addition of heavy metal salts or radiopaque inserts to denture base resins. None of these attempts has been entirely successful.Elimination of dentures as foreign bodies requires a greater effort toward preventive measures by the dentist and the patient. When dentures are swallowed or inhaled, the dentist should immediately seek medical assistance for the patient. The common symptomless period following ingestion or aspiration should not lead the dentist to believe that there will not be serious subsequent complications.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 5 (1971), S. 335-357 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Physical properties were determied for radiopaque composite denture base materials consisting of poly (methyl methacrylate) as thematrix and 30, 40, and 50% by weight fo a singlane-treated barum fluoride-containing glass powder as the reinforcing filler. Specimens without glass were include for comparision.All of the materials met the requirements of Amerrican ental Association Specification No. 12 for Denture Base Polymer except that t6he material containing 50% glass had less deflection than the minimum required at the 5000-gm load in transverse testing.There was little or no difference among thematerials with respect to hardness, in denation resistance, water sorption, color stability, and resistance to drop impact.Addition of glass of the 30% level decreased the transevers strenght while 50% means with no glass. In general, the addition of glass increased the time to reach only slight effect on densities, and Young's, bulk, shear, and flexural moduli, had only slight effect on solubility and decreased the cold-cure repairability and the coefficient of linear thermal expanision.The solubility of the glass power was aboutfour times that of powdered porcelain teeth after 24 hr, and totaled 0.55% afeter 5 days.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 18 (1997), S. 1371-1391 
    ISSN: 0192-8651
    Schlagwort(e): molecular mechanics ; MM3 ; PARTS ; force field ; protonated amine ; ab initio ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Informatik
    Notizen: The geometries and vibrational frequencies of 11 training molecules containing the ammonium ion moiety were calculated at the MP2/6-31+G* level of theory. Various torsional energy profiles were also calculated using this basis set. From those ab initio calculations, a molecular mechanics (MM3) force field was developed using our Parameter Analysis and Refinement Toolkit System (PARTS). Using this set of parameters, the MM3 force field was found to well reproduce the molecular geometries and vibrational spectra for the all training molecules. CPU time was reduced from days to seconds. The availability of this new force field dramatically increases the feasibility of the computer-assisted drug design involving ammonium and protonated amino groups.   © 1997 by John Wiley & Sons, Inc.   J Comput Chem 18: 1371-1391, 1997
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 19 (1998), S. 1387-1401 
    ISSN: 0192-8651
    Schlagwort(e): acyl halides ; MM3 ; ab initio calculations ; IR ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Informatik
    Notizen: A newly developed acyl halide molecular mechanics (MM3) force field can accurately calculate molecular geometry, usually to within experimental error. The new force field can also calculate vibrational frequencies. The acyl halides studied were formyl halides, acetyl halides, propionyl halides, n-butyryl halides, 2-methylpropionyl halides, and 2,2-dimethylpropionyl halides. The rms deviation for vibrational frequencies was 28 cm-1.   © 1998 John Wiley & Sons, Inc.   J Comput Chem 19: 1387-1401, 1998
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 19 (1998), S. 1370-1386 
    ISSN: 0192-8651
    Schlagwort(e): acyl halides ; MM3 ; ab initio calculations ; conformational analysis ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Informatik
    Notizen: A new molecular mechanics (MM3) force field has been developed based on various experimental data as well as ab initio calculations. Computer-generated molecular structures and energy values were compared with experimentally determined data. The acyl halides studied were formyl halides, acetyl halides, propionyl halides, n-butyryl halides, 2-methylpropionyl halides, and 2,2-dimethylpropionyl halides. The rms deviations were 0.005 Å and 1.06° for bond lengths and bond angles, respectively. MM3 was in good overall agreement with the available structural, conformational, and thermodynamic data.   © 1998 John Wiley & Sons, Inc.   J Comput Chem 19: 1370-1386, 1998
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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