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  • Chemistry  (1)
  • lower mantle  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Single molecule force spectroscopy on poly(vinyl alcohol) by atomic force microscopy (1998)
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 19 (1998), S. 609-611 
    Details
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The elastic properties of poly(vinyl alcohol) (PVA) were investigated on the nanoscale using the new technique of single molecule force spectroscopy by atomic force microscopy (AFM). It was found that the elastic properties of PVA molecules scale linearly with their contour lengths. This finding corroborates that the deformation of individual PVA chains is measured. The force spectra of PVA show a kink at around 200 pN and cannot be fitted by an extended Langevin function. The deviation of the elastic behavior of PVA from a freely jointed chain model may indicate the presence of a suprastructure of PVA in NaCl solution.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 2
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    Stability and Solubility of the FeAlO3 Component in Bridgmanite at Uppermost Lower Mantle Conditions (2021)
    Details
    Publication Date: 2021-07-26
    Description: We report the stability and solubility of the FeAlO3 component in bridgmanite based on phase relations in the system MgSiO3-FeAlO3 at 27 GPa and 2000 K using a multi-anvil apparatus combined with in situ synchrotron X-ray diffraction measurements. The results demonstrate that the FeAlO3 component dominates Fe3+ and Al3+ substitution in bridgmanite, although trace amounts of oxygen- and Mg-site vacancy components are also present. Bridgmanite with more than 40 mol% FeAlO3 transforms into the LiNbO3-type phase upon decompression. The FeAlO3 end-member decomposes into corundum and hematite and does not form single-phase bridgmanite. We determined the maximum solubility of the FeAlO3 component in bridgmanite at 27 GPa and 2000 K to be 67 mol%, which is significantly higher than previously reported values (25–36 mol%). We determined the partial molar volume (27.9 mol/cm3) and bulk modulus (197 GPa) of hypothetical FeAlO3 bridgmanite, which are significantly higher and lower than those of AlAlO3 and FeSiO3 bridgmanite, respectively. The non-ideality of MgSiO3-FeAlO3 solid solution (W = 13 kJ/mol, where W is the interaction parameter) is significantly larger than that for MgSiO3-AlAlO3 (5 kJ/mol) and MgSiO3-FeSiO3 (3 kJ/mol) solid solutions. The rapid decrease in abundance of the MgAlO2.5 component in bridgmanite with increasing pressure is enhanced by the presence of the FeAlO3 component. The FeAlO3 content in pyrolite and mid-ocean ridge basalt is far below its solubility limit in bridgmanite and provides new insight into the mineralogy of the lower mantle.
    Keywords: 549 ; bridgmanite ; FeAlO3 solubility ; the LiNbO3-type phase ; non-ideality ; lower mantle
    Language: English
    Type: article
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    CITATION GEO-LEO
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