ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The gas-phase reaction of bornyl acetate (bicyclo[2,2,1]-heptan-2-ol-1,7,7-trimethyl-acetate) with hydroxyl radical has been studied. A relative method was used to determine the rate constant for this reaction, with n-octane as reference compound.Methyl nitrite photolysis experiments were carried out in an environmental smog chamber at atmospheric pressure and (294±2) K. The rate constant determined for bornyl acetate is k=(13.9±2.2)×10-12 cm3 molecule-1 s-1.The experimental rate constant has been compared with the rate constants calculated with the structure-activity relationship (SAR) and with the evolution trend of the acetate rate constants. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 497-502, 1998
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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