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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 16 (1990), S. 407-411 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Polyvinylcarbazole, polyvinylpyridine and polyethersulphone films have been bombarded with 150 keV Ar+ ion beams and the midified surfaces have been characterized chemically by ESCA and REELS (reflection electron energy loss spectroscopy).In the explored fluence range (5 × 1012-1 × 1016 ions cm-2), several types of chemical reactions, such as dehydrogenation, loss of heteroatopms, loss of aromaticity via ring opening, reduction, etc., heve been shown to occur, depending on the chemical structure of the pristine system.For the polyethersulphone, a comparison of the chemical effects produced by electrons, photons and ion beams of comparable energy (∼1 keV) and fluence (1015-10-16 ions cm-2) also has been reported.The results are discussed in terms of energy deposition mechanisms, as well as chemical grounds. In particular, they allow a further assessment to be made of the field of chemical reactions induced by ion beams. Furthermore, they show that for a given dose the chemical modification of a polymer surface by an ion beam is much greater than that expected for electrons or photons.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-07-13
    Description: The Thermal Energy Conversion Branch at NASA Glenn Research Center (GRC) is supporting the development of high-efficiency power convertors for use in Radioisotope Power Systems (RPS). Significant progress was made towards such a system that utilized Stirling conversion during the 2001 to 2015 timeframe. Flight development of the Advanced Stirling Radioisotope Generator (ASRG) was cancelled in 2013 by the Department of Energy (DOE) and NASA Headquarters primarily due to budget constraints, and the Advanced Stirling Convertor (ASC) technology contract was subsequently concluded in 2015. A new chapter of technology development has recently been initiated by the NASA RPS Program. This effort is considering all dynamic power convertor options, such as Stirling and Brayton cycles. Four convertor development contracts supporting this effort were awarded in 2017. The awarded contracts include two free-piston Stirling, one thermoacoustic Stirling, and one turbo-Brayton designs. The technology development contracts each consist of up to three phases: Design, Fabricate, and Test. As of May 2018, all contracts have completed the Design Phase, and each underwent a design review with an independent review board. Three of the contracts are planned to execute the Phase 2 option for fabrication. Convertors manifesting from these development efforts will then undergo independent validation and verification at NASA facilities, which will consist of convertor performance and RPS viability demonstrations. Example tests include launch vibration simulation, performance mapping over the environmental temperature range, and static acceleration exposure. In parallel with this renewed development effort, NASA GRC is still demonstrating free-piston Stirling convertor technology using assets from previous projects. The Stirling Research Laboratory (SRL) is still operating several convertors from previous development projects which have similarities and relevance to current contract designs. Four of which are flexure-bearing based, and another six are gas-bearing based. One of the flexure-bearing convertors has accumulated over 110,000 hours of operation, and holds the current record for maintenance-free heat-engine run-time. Another flexure-bearing convertor was recently manually shutdown after 105,620 hours of operation, then disassembled and inspected. This inspection produced a wealth of information about the effects of this amount of runtime on the technology's components. One of the engineering unit flexure-bearing convertors recently underwent launch simulation vibration test, a static acceleration exposure up to 20 g, and was then placed on extended operation. Amongst the gas-bearing convertors, the longest running unit has accumulated over 70,000 hours of operation. Four high-fidelity gas-bearing convertors from the ASRG project are still operating continuously, for which the longest runtime has reached 28,000 hours.
    Keywords: Nuclear Physics; Mechanical Engineering
    Type: GRC-E-DAA-TN57597 , International Energy Conversion Engineering Conference; Jul 07, 2018 - Jul 13, 2018; Cincinnati, OH; United States
    Format: application/pdf
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