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  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The composition and sequence distribution of copolymers of maleic anhydride (MA) with p-methoxystyrene (p-MST) and p-chlorostyrene (p-CST) prepared in ethyl methyl ketone at 50 ± 0,1°C were analysed using 13C DEPT NMR techniques, in order to compare the applicability of composition and sequence distribution data to the study of the mechanism of copolymerisation using the terminal, penultimate and complex-participation models. In the case of the strongly alternating copolymerisation of p-MST with MA, the comparison of models on the basis of sequence distribution data was found to be better at separating each model in terms of its applicability, with the complex-participation model providing the best fit to the data. In the case of the less strongly alternating copolymerisation of p-CST with MA, neither method of comparison could clearly distinguish between the penultimate and complex-participation models.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 14 (1995), S. 244-256 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 56 (1995), S. 667-675 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Curing reactions of certain laminates involve a series of chemical structure changes which occur with increasing temperature and/or pressure. This paper describes the use of a midinfrared chalcogenide fiber to monitor the lamination of polymer prepregs in an autoclave. The fiber optic was used both as a wave guide and as a sensing element for acquiring evanescent wave spectra. The spectra were measured by embedding the fiber optic in a polymer prepreg package. The polymer prepregs studied include epoxy, polyimide, and bismaleimide triazine (BT) resins. The degree of cure and an understanding of the kinetic processes were obtained from the absorbance changes in specific bands. This in situ sampling technique demonstrates a new area of Fourier transform infrared (FTIR) spectroscopy for following the formation of polymeric bonds. © 1995 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Deuteration studies, hydration studies, melting studies and model compound studies are utilized to assign and interpret the 800-900 cm-1 region of the Raman spectra of the phospholipids dipalmitoyl phosphatidylcholine and dipalmitoyl phosphatidylethanolamine. Head group Raman bands in this region are shown to be sensitive to hydration and melting. The acyl carbon-carbon stretches, assigned to Raman bands appearing at 860-890 cm-1, are shown to be sensitive probes of molecular packing order, specifically in the acyl interface region.
    Additional Material: 5 Ill.
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  • 5
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Vibrational frequencies of diethyl phosphate were calculated for rotamers for which the dihedral angle about the P—O and C—O bonds varied. The frequencies predicted for the symmetric and antisymmetric O—P—O stretches, the symmetric and antisymmetric ionic PO2- stretches, and the C—C stretches are found to be sensitive to the P—O and C—O dihedral angles. The results of Raman temperature and solvent studies of diethyl phosphate are reported and are found to be in good agreement with the conclusions obtained from the normal coordinate analyses. Frequencies of diethyl phosphate rotamers having the geometries of crystalline glycerophosphorylcholine (GPC), crystalline GPC CdCCl2, and amorphous GPC CdCl2 were calculated and compared to the Raman spectra of these phospholipid head group models. The normal coordinate analyses are in good agreement with Raman spectra. These results indicate that the observed frequencies of phosphate group vibrations may be compared to the normal coordinate analyses of diethyl phosphate rotamers to monitor conformation in phospholipid head groups (and other organic ortho -phosphates). The Raman symmetric O—P—O stretch bandwidth may be used to monitor rotational freedom or broadening due to the distribution of differing conformations.
    Additional Material: 9 Ill.
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  • 6
    Publication Date: 2019-08-14
    Description: Many tons of dust grains, including samples of asteroids and comets, fall from space into the Earth's atmosphere each day. NASA periodically collects some of these particles from the Earth's stratosphere using sticky collectors mounted on NASA's high-flying aircraft. Sometimes, especially when the Earth experiences a known meteor shower, a special opportunity is presented to associate cosmic dust particles with a known source. NASA JSC's Cosmic Dust Collection Program has made special attempts to collect dust from particular meteor showers and asteroid families when flights can be planned well in advance. However, it has rarely been possible to make collections on very short notice. In 2012, the Draconid meteor shower presented that opportunity. The Draconid meteor shower, originating from Comet 21P/Giacobini-Zinner, has produced both outbursts and storms several times during the last century, but the 2012 event was not predicted to be much of a show. Because of these predictions, the Cosmic Dust team had not targeted a stratospheric collection effort for the Draconids, despite the fact that they have one of the slowest atmospheric entry velocities (23 km/s) of any comet shower, and thus offer significant possibilities of successful dust capture. However, radar measurements obtained by the Canadian Meteor Orbit Radar during the 2012 Draconids shower indicated a meteor storm did occur October 8 with a peak at 16:38 (+/-5 min) UTC for a total duration of approximately 2 hours.
    Keywords: Lunar and Planetary Science and Exploration
    Type: ARES Biennial Report 2012 Final; 37-40; JSC-CN-30442
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  • 7
    Publication Date: 2019-07-19
    Description: The dynamical and physical characteristics of a meteoroid affects its behavior in the atmosphere and the damage it does to spacecraft surfaces. Accurate environment models must therefore correctly describe the speed, size, density, and direction of meteoroids. However, the measurement of dynamical characteristics such as speed is subject to observational biases, and physical properties such as size and density cannot be directly measured. De-biasing techniques and proxies are needed to overcome these challenges. In this presentation, we discuss several recent improvements to the derivation of the meteoroid velocity, directionality, and bulk density distributions. We derive our speed distribution from observations made by the Canadian Meteor Orbit Radar. These observations are de-biased using modern descriptions of the ionization efficiency and sharpened to remove the effects of measurement uncertainty, and the result is a meteoroid speed distribution that is skewed slower than in previous analyses. We also adopt a higher fidelity density distribution than that used by many older models. In our distribution, meteoroids with T(sub J) less than 2 are assigned to a low-density population, while those with T(sub J) greater than 2 have higher densities. This division and the distributions themselves are derived from the densities reported by Kikwaya et al. (2009, 2011). These changes have implications for the environment. For instance, helion and antihelion meteors have lower speeds and higher densities than apex and toroidal meteors. A slower speed distribution therefore corresponds to a sporadic environment that is more completely dominated by the helion and antihelion sources than in previous models. Finally, assigning these meteors high densities further increases their significance from a spacecraft damage perspective.
    Keywords: Lunar and Planetary Science and Exploration
    Type: M17-6169 , American Geophysical Union (AGU) Fall Meeting; Dec 11, 2017 - Dec 15, 2017; New Orleans, LA; United States
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  • 8
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    In:  http://aquaticcommons.org/id/eprint/15087 | 403 | 2014-05-28 03:22:35 | 15087 | United States National Marine Fisheries Service
    Publication Date: 2021-07-02
    Description: The population structure of walleye pollock (Theragrachalcogramma) in the northeastern Pacific Ocean remains unknown. We examined elemental signatures in the otoliths of larval and juvenile pollock from locations in the BeringSea and Gulf of Alaska to determine if there were significant geographic variations in otolith compositionthat may be used as natural tags of population affinities. Otoliths were assayed by using both electron probemicroanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (ICP-MS). Elements measured at the nucleus of otoliths by EPMA and laser ablation ICP-MS differed significantly among locations. However, geographicgroupings identified by a multivariate statistical approach from EPMA and ICP-MS were dissimilar, indicating that the elements assayed by each technique were controlled by separate depositional processes within the endolymph. Elemental profiles across the pollock otoliths were generally consistent at distances up to 100 μm from the nucleus. At distances beyond 100 μm, profiles varied significantly but were remarkably consistent among individuals collected at each location. These data may indicate that larvae from various spawning locations are encountering water masses with differing physicochemicalproperties through their larval lives, and at approximately the same time. Although our results are promising, we require a better understanding of the mechanisms controlling otolith chemistry before it will be possibleto reconstruct dispersal pathways of larval pollock based on probe-based analyses of otolith geochemistry. Elemental signatures in otoliths of pollock may allow for the delineation of fine-scale population structure in pollock that has yet to be consistently revealed by using population genetic approaches.
    Keywords: Chemistry ; Fisheries
    Repository Name: AquaDocs
    Type: article , TRUE
    Format: application/pdf
    Format: application/pdf
    Format: 604-616
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  • 9
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    NOAA/National Marine Fisheries Service
    In:  http://aquaticcommons.org/id/eprint/2768 | 403 | 2011-09-29 18:26:43 | 2768 | United States National Marine Fisheries Service
    Publication Date: 2021-06-28
    Description: This report describes the proximate compositions (protein, moisture, fat, and ash) and major fatty acid profiles for raw and cooked samples of 40 southeastern finfish species. All samples (fillets) were cooked by a standard procedure in laminated plastic bags to an internal temperature of 70'C (lS8'F). Both summarized compositional data, with means and ranges for each species, and individual sample data including harvest dates and average lengths and weights are presented. When compared with raw samples, cooked samples exhibited an increase in protein contentwith an accompanying decrease in moisture content. Fat content either remained approximately the same or increased due to moisture loss during cooking. Our results are discussed in reference to compositional data previouslypublished by others on some of the same species. Although additional data are needed to adequately describe the seasonal and geographic variations in the chemical compositions of many of these fish species, the results presented here should be useful to nutritionists, seafood marketers, and consumers.(PDF file contains 28 pages.)
    Keywords: Fisheries ; Biology ; Chemistry
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
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  • 10
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    Florida Geological Survey | Tallahassee, FL
    In:  http://aquaticcommons.org/id/eprint/639 | 3 | 2020-08-24 02:23:46 | 639 | Florida Geological Survey
    Publication Date: 2021-07-01
    Description: The U. S. Geological Survey made a comprehensiveinvestigation of the water resources of Brevard Countyfrom 1954 to 1958. The purposes of this investigation were:(1) to determine the occurrence and chemical quality ofwater in the streams and lakes, (2) to determine the locationand the thickness of aquifers, and (3) to determine theoccurrence and chemical quality of the ground water. Duringthe period from 1933 to 1954, water records were collectedfrom a few stream-gaging stations and a few observationwells. The purpose of this report is to present basic datacollected during these investigations. (Document has 188 pages.)
    Keywords: Limnology ; Earth Sciences ; Chemistry ; water quality ; streams ; lakes ; aquifers ; Brevard County ; Florida
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
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