ISSN:
0044-2313
Keywords:
Lithium hydroxide/lithium chloride system
;
crystal structure of Li4Cl(OH)3 and Li2Cl(OH)
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Unusual Coordination Polyhedra around Oxygen in Li4Cl(OH)3The pseudobinary system LiOH/LiCl was investigated by X-ray methods. Two compounds, Li4Cl(OH)3 and Li2Cl(OH), were obtained. The crystal structure of Li4Cl(OH)3 solved by single-crystal methods is delt with. For Li2Cl(OH) powder diffraction data are given:Li4Cl(OH)3: P21/m, Z = 2, a = 5.4096(8) Å, b = 7.382(2) Å, c = 6.2076(8) Å, β = 94.40(1)°, Z(Fo) with (Fo)2 ≧ 3σ(Fo)2 = 483, Z (parameter) = 50, R/Rw = 0.022/0.025 Li2Cl(OH): Pmma, Z = 2, a = 7.680(8) Å, b = 4.001(7) Å, c = 3.899(6) ÅThe hydroxide rich compound crystallizes in a new type of structure which contains puckered layers ∞2[Li4(OH)3+] connected via chloride ions.
Notes:
Das pseudobinäre System LiOH/LiCl wurde röntgenographisch untersucht. Zwei Verbindungen, Li4Cl(OH)3 und Li2Cl(OH), ließen sich nachweisen. Die Struktur von Li4Cl(OH)3 wurde an Einkristallen aufgeklärt, für Li2Cl(OH) liegen nur Pulverdaten vor:Li4Cl(OH)3: P21/m, Z = 2, a = 5,4096(8) Å, b = 7,382(2) Å, c = 6,2076(8) Å, β = 94,40(1)°, Z(Fo) mit (Fo)2≧3σ(Fo)2 = 483, Z (Parameter) = 50, R/Rw = 0,022/0,025 Li2Cl(OH): Pmma, Z = 2, a = 7,680(8) Å, b = 4,001(7) Å, c = 3,899(6) ÅDie hydroxidreichere Verbindung kristallisiert in einem neuen Strukturtyp, der gewellte Schichten von ∞2[Li4(OH)3+] enthält, die über Chloridionen verknüpft sind.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19946200311
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