ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Engineering General  (15)
  • Chemistry  (12)
  • FLUID MECHANICS AND HEAT TRANSFER  (4)
  • Magnetism  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 34 (1992), S. 823-836 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A domain-adaptive technique and an iterative, block bidiagonal method are used to analyse the unsteady dynamics of annular liquid membranes subject to fluctuations in the mass injected into the volume enclosed by the membranes. The domain-adaptive technique maps the unknown, time-dependent, curvilinear geometry of the liquid membrane into a unit interval. The condition that the membrane's radius is zero at the convergence point is used to determine the convergence length, which is governed by an ordinary differential equation. This equation is solved iteratively together with those which govern the fluid dynamics equations. A block bidiagonal technique is used to determine the mass per unit length, radius, and axial and radial velocity components of the membrane. It is shown that the pressure of the gases enclosed by the liquid membrane responds instantaneously to changes in and exhibits the same periodic behaviour as the mass injection rate. The convergence length takes a delay time to respond to the mass injection rate fluctuations. The magnitude of this delay time increases as the Froude and Weber numbers and the nozzle exit angle are increased. The amplitude of the oscillations of both the convergence length and the pressure coefficient increases as the pressure difference across the membrane and the amplitude of the mass injection rate fluctuations are increased.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Der thermische Abbau von Poly-N-vinyl-carbazol (PVK) wurde mittels „flash“-Pyrolyse, kontrollierter Pyrolyse und dynamisch-thermogravimetrischer Analyse untersucht. Die Analyse der Abbauprodukte erfolgte über Gas-Flüssig-Chromatographie sowie Massenspektrometrie als Trennungs- und Identifizierungsverfahren. Das untersuchte PVK wurde durch radikalische Polymerisation in Benzol mit AIBN als Katalysator dargestellt.Aus den Versuchsergebnissen ergibt sich, daß PVK fast vollkommen über einen stufenweisen „unzipping“ Mechanismus in das Monomere zerfällt. Die Zusammensetzung der Pyrolysate ermöglicht eine Formulierung des Abbaumechanismus des Polymeren. Mit Hilfe des Verfahrens der multiplen Aufheizgeschwindigkeiten wurde die Kinetik des thermischen Abbaus untersucht. Die Bruttoaktivierungsenergie der Depolymerisation wurde zu 40 kcal/mol gemessen und für die Reaktionsordnung wurde ungefähŕ 1 gefunden.Es werden einige thermodynamische Betrachtungen aufgeführt, um den Wert der Aktivierungsenergie des gesamten Prozesses zu erklären. Es wird ein Mechanismus vorgeschlagen.
    Notes: The thermal degradation of poly-N-vinyl-carbazol (PVK) has been studied using flash pyrolysis, controlled pyrolysis and programmed thermogravimetry analysis techniques. The degradation products have been analyzed using gas-liquid chromatography and mass spectrometry as separation and characterization techniques. The examined PVK has been prepared by free radical polymerization in benzene using AIBN as catalyst.It is shown from experimental results that PVK breaks up almost completely into the monomer through a stepwise unzipping mechanism. The composition of the pyrolyzate allows to propose a mechanism for the polymer degradation. Thermal degradation rates have been analyzed using a multiple heating rates procedure. A value of 40 kcal/mol has been found for the overall activation energy of depolymerization and a value approximately equal to one for the order of reaction.Some thermodynamic considerations have been made in order to explain the value of the activation energy of the whole process. A mechanism is suggested.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 25 (1987), S. 1099-1111 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dielectric relaxation behavior of a nonaligned and an aligned liquid-crystalline (LC) polymer are reported for the ranges 10-3.5 to 105 Hz and 274-363 K. Multiple processes (δ and α) are observed that follow a Vogel equation for the temperature dependence related to the apparent glass transition temperature. The occurrence of these processes and the variation in their relaxation strengths as sample alignment is changed is interpreted in terms of a molecular theory for the dielectric behavior of a LC polymer that involves the director order parameter Sd, the mesophase order parameter S, the dipole moment components of the mesogenic head groups, and their associated relaxation functions.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 1075-4261
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: The study of the surface enhanced Raman spectroscopy (SERS) excitation profiles of 1,5-dimethylcytosine on metal colloids allows a more detailed determination of the behavior of the functional groups of this molecule in the adsorption process on the metal supports. Silver has shown its effectiveness and selectivity as a support for this technique from the point of view of its stability and capability to enhance the Raman signal coming from the adsorbate. The results are discussed in terms of the two well-known theories proposed up to now to explain the SERS phenomenon: electromagnetic and chemical (or charge transfer) models. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 1075-4261
    Keywords: 9-aminoacridine ; fluorescence ; SERS ; dimerization ; excimer ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: Fluorescence spectroscopy and surface-enhanced Raman spectroscopy (SERS) have been applied to study the aggregation and excimer emission of 9-aminoacridine (9AA) and 9-aminoacridine hydrochloride (9AA-HCl) in aqueous solution and on silver colloids. The effect of the drug concentration, pH, and chloride concentration on these processes has been investigated. The excimer emission of 9AA is connected to the dimerization of this drug in solution: the formation of 9AA dimers is greatly favored when the drug is under the amino form at neutral and acidic pH, while at alkaline pH the imino 9AA form tends to form large-sized aggregates which cannot be excited to render excimer emission. 9AA is adsorbed on the silver surface under two different forms: strongly and weakly attached 9AA, each one corresponding to the different drug tautomers: imino and amino. The interaction of 9AA with silver induces a charge transfer from the adsorbate to the metal leading to a remarkable fluorescence quenching, a basicity decrease of the adsorbed drug and a considerable weakening of the dimer-excimer emission. Furthermore, an attribution of the main Raman features appearing in the SERS spectra has been proposed, providing marker bands for the imino and amino 9AA tautomers, and a mechanism for the molecular dimerization is also suggested. © 1998 John Wiley & Sons, Inc. Biospectroscopy 4: 327-339, 1998
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biospectroscopy 3 (1997), S. 449-455 
    ISSN: 1075-4261
    Keywords: surface-enhanced Raman spectroscopy ; γ-aminobutyric acid ; Raman spectra ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: The surface-enhanced Raman spectroscopy (SERS) of γ-aminobutyric acid (GABA) adsorbed on silver colloids in H2O and D2O were recorded and analyzed. When the concentration is greater than 10-3 M, the adsorbed species is the anionic form of the amino acid that interacts with the surface through both functional groups. According to the vibrational interpretation of the spectra, it is assumed that at concentrations in the order of or less than 10-3 M, GABA undergoes chemical transformations, which increase upon dilution, and spectra are recorded that are the result of the competitive adsorption between the amino acid in its anionic form and the products resulting from the chemical transformations. © 1997 John Wiley & Sons, Inc. Biospectroscopy 3: 449-455, 1997
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 12 (1991), S. 881-894 
    ISSN: 0271-2091
    Keywords: Liquid membranes ; Adaptive finite difference methods ; Integrodifferential equations ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Two domain-adaptive finite difference methods are presented and applied to study the dynamic response of incompressible, inviscid, axisymmetric liquid membranes subject to imposed sinusoidal pressure oscillations. Both finite difference methods map the time-dependent physical domain whose downstream boundary is unknown onto a fixed computational domain. The location of the unknown time-dependent downstream boundary of the physical domain is determined from the continuity equation and results in an integrodifferential equation which is non-linearly coupled with the partial differential equations which govern the conservation of mass and linear momentum and the radius of the liquid membrane. One of the finite difference methods solves the non-conservative form of the governing equations by means of a block implicit iterative method. This method possesses the property that the Jacobian matrix of the convection fluxes has an eigenvalue of algebraic multiplicity equal to four and of geometric multiplicity equal to one. The second finite difference procedure also uses a block implicit iterative method, but the governing equations are written in conservation law form and contain an axial velocity which is the difference between the physical axial velocity and the grid speed. It is shown that these methods yield almost identical results and are more accurate than the non-adaptive techniques presented in Part I. It is also shown that the actual value of the pressure coefficient determined from linear analyses can be exceeded without affecting the stability and convergence of liquid membranes if the liquid membranes are subjected to sinusoidal pressure variations of sufficiently high frequencies.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 1293-1314 
    ISSN: 0271-2091
    Keywords: chemical reactors ; annular liquid jets ; grid generation ; mass absorption ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A numerical study of Hopf bifuractions in annular liquid jets with mass transfer is presented. The study is based on the asymptotic equations which govern the dynamics of inviscid, incompressible, thin, annular liquid jets and on equilibrium conditions for mass transfer at the jet's inner and outer interfaces. It is shown that the amplitude of the time-periodic motion that results from the Hopf bifurcation increases whereas its frequency decreases as the solubility ratio is increased.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 961-978 
    ISSN: 0271-2091
    Keywords: planar liquid sheets ; perturbation methods ; film casting ; film coating ; plane stagnation flows ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Asymptotic methods are employed to derive the leading-order equations which govern the fluid dynamics of time-dependent, incompressible, planar liquid sheets at low Reynolds numbers using as small parameter the slenderness ratio. Analytical and numerical solutions of relevance to both steady film casting processes and plane stagnation flows are obtained with the leading-order equations. It is shown that for steady film casting processes the model which accounts for both gravity and low-Reynolds-number effects predicts thicker and slower planar liquid sheets than those which neglect a surface curvature term or assume that Reynolds number is zero, because the neglect of the curvature term and the assumption of zero Reynolds number are not justified at high take-up velocities owing to the large velocity gradients that occur at the take-up point. It is also shown that for Reynolds number/Froude number ratios larger than one, models which neglect the surface curvature or assume a zero Reynolds number predict velocity profiles which are either concave or exhibit an inflection point, whereas the model which accounts for both curvature and low-Reynolds-number effects predicts convex velocity profiles. For plane stagnation flows it is shown that models which account for both low-Reynolds-number and curvature effects predict nearly identical results to those of models which assume zero Reynolds number. These two models also predict a faster thickening of the planar liquid sheet than models which account for low- Reynolds-number effects but neglect the surface curvature. This curvature term is very large near the stagnation point and cannot be neglected there. It is also shown that the thickening of the sheet occurs closer to the stagnation point as the Reynolds number/Froude number ratio is increased, i.e. as the magnitude of the gravitational acceleration is increased. In addition it is shown that large surface tension introduces a third-order spatial derivative in the axial momentum equation at leading order.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 1089-1102 
    ISSN: 0271-2091
    Keywords: piecewise-linearized methods ; two-point boundary value problems ; singular perturbations ; finite differences ; finite elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Piecewise-linearized methods for the solution of two-point boundary value problems in ordinary differential equations are presented. These problems are approximated by piecewise linear ones which have analytical solutions and reduced to finding the slope of the solution at the left boundary so that the boundary conditions at the right end of the interval are satisfied. This results in a rather complex system of non-linear algebraic equations which may be reduced to a single non-linear equation whose unknown is the slope of the solution at the left boundary of the interval and whose solution may be obtained by means of the Newton-Raphson method. This is equivalent to solving the boundary value problem as an initial value one using the piecewise-linearized technique and a shooting method. It is shown that for problems characterized by a linear operator a technique based on the superposition principle and the piecewise-linearized method may be employed. For these problems the accuracy of piecewise-linearized methods is of second order. It is also shown that for linear problems the accuracy of the piecewise-linearized method is superior to that of fourth-order-accurate techniques. For the linear singular perturbation problems considered in this paper the accuracy of global piecewise linearizat ion is higher than that of finite difference and finite element methods. For non-linear problems the accuracy of piecewise-linearized methods is in most cases lower than that of fourth-order methods but comparable with that of second-order techniques owing to the linearization of the non-linear terms.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...