ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Coordination Compounds of Boron Trialkyls. II. On the Complex Formation between Boron Triallyls and Tertiary AminesIt is reported on complexes of triallyl, trimethallyl, and tricrotyl boron with N,N-,N′,N′-tetraethylethylene diamine, pyridine, and 2,2′-bipyridyl. Whilst only 1:1 complexes exist with pyridine, 1:1 and 2:1 complexes are formed with tetraethylethylene diamine. Bipyridyl reacts with triallyl boron with formation of the boronium salt [(all)2B(dipy)][B(all)4].
Notes:
Es wird über Reaktionen von Bortriallyl, -trimethallyl und -tricrotyl mit N,N,N′,N′-Tetraäthyläthylendiamin, Pyridin und 2,2′-Dipyridyl berichtet. Mit Pyridin werden stets 1:1-Komplexe, mit Tetraäthyläthylendiamin 1:1- und 2:1-Komplexe von EDA-Typ gebildet. Mit Dipyridyl reagiert Bortriallyl zu einem Boroniumsalz der Formel [(all)2B(dipy)][B(all)4].
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19774280128
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