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  • Chemical Engineering  (1)
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    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1627-1636 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Supercritical water oxidation of isopropyl alcohol was investigated in a pilot-scale reactor. A computational fluid-dynamics model developed reveals the detailed flow field, chemical-component distribution, temperature distribution, and salt-particle trajectories in the reactor flow domain. The near-wall fluid temperature from the numerical analysis was compared with experimental temperature data. The temperature comparison was within a 3% error band. The effect of the chemical kinetic rate was investigated for four different rates. Turbulent salt-particle trajectories were also calculated to investigate the effect of particle sizes on salt deposit on the wall. Also, a method of calculating the adiabatic reaction temperature was developed to estimate reaction temperatures prior to a full numerical simulation.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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