ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A two-parameter, corresponding-states form for direct correlation function integrals in liquids is applied to many types of systems with one substance being supercritical. This gives a quantitative correlation for volumetric behavior, pure and mixed solvent Henry's constants, and Henry's Law deviations over wide ranges of conditions using only pure-component information and a single binary parameter. Details of the method and results are given for H2, N2, CO, CH4, and other gases in pure and mixed simple, polar, and aqueous solvents and coal oils. Because of its reliable predictive capability, the present approach can serve as a generator of data for parameter estimation by other models such as equations of state.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690331216
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