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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 403-403 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 9 (1971), S. 2131-2135 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: It is shown that the glass transition temperatures of the ionic acrylates are subject to the same correlation as found for the phosphates, silicates, and ionenes; the equation is Tg = 730 (q/a) - 67, where q is the cation charge and a the separation between centers of charge for the cation and anion.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 940-946 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The electrical conductivity and the dissipation factor of silicone rubber vulcanized by the condensation reaction of α,ω-dihydroxypolysiloxane with ethoxysilane, using dibutyltin dilaurate as a catalyst, were studied. Rubber specimens, with different amounts of catalyst, were prepared using various vulcanization times and then heat treated in dry or wet atmospheres containing oxygen and nitrogen. The electrical properties of these specimens were measured at 20 to 200°C in dry air. The amounts of residual catalysts and unreacted ethoxy groups were analyzed by colorimetric and gas chromatographic methods. Factors influencing the specimen electrical properties were discussed in terms of preparation conditions and amount of residual compounds.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 1717-1728 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of dehydration and decarboxylation as well as the glass transition temperature as a function of anhydride content were measured for poly(acry1ic acid). It was found that the glass transition of PAA is of the order of 103°C and increases with increasing anhydride content, reaching an extrapolated value of 140°C for the pure linear anhydride. Anhydride formation is a firstsrder reaction, as is also decarboxylation, the latter being much slower than the former. The rate constants are for dehydration, ka = 2.5 × 109 exp {-26000/RT}; for decarboxylation, kd = 2.9 × 108 exp {-27000/RT}. Anhydride formation occurs primarily by an intramolecular process.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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