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  • 1
    ISSN: 1572-879X
    Keywords: methanethiol ; Mo–S‐based catalyst ; H2S‐containing syngas ; transition metal oxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The catalysts K2MoS4/SiO2 promoted with transition metal oxides Fe2O3, CoO, NiO and MnO2 were prepared and used to catalyze the synthesis of methanethiol from H2S‐containing syngas. The results of activity assay show that the catalysts promoted with Fe2O3, CoO and NiO can remarkably increase the hour space yield of methanethiol. Nevertheless, MnO2 was found to have a disadvantageous effect on the selectivity of methanethiol. The results of XRD and XPS characterization indicate that the addition of the transition metal oxides promoters is in favor of the formation of a Mo–S–K active phase and also retards the decomposition of K2MoS4 to MoS2, thereby suppressing both the deep reduction of Mo species and the formation of (S–S)2 species, which are reflected by the increment of the concentration ratios of both Mo6+/Mo4+ and S2/(S–S)2.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1590-1599 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cohesive (Group C) particles have been widely used in various industries. To handle and process such fine particles, a clear understanding of the flow behavior and interparticle force, is needed. To achieve that objective, a Laser Doppler Anemometer system was used to measure particle velocity, fluctuating velocity, and size and extent of agglomeration or cluster formation of particles in a dilute gas/fine oil shale particle flow system with particle density of 2,082 kg/m3, average particle volumetric concentration of 1.5%, and average particle mass flux of about 100 kg/m2·s in a controlled-moisture environment. The flow behavior of the particles was also studied for a mixture of 99% shale particles and 1% antistatic agent (Larostat powder, a quaternary ammonium compound) to examine the role of electrostatic force in gas/cohesive particle flow behavior. The addition of Larostat powder significantly reduced the electrostatic force and, in turn, made Group C particles behave similar to Group A or in some cases to Group B particles. In addition, our experimental data showed that the Maxwellian distribution function is a reasonable assumption to describe the velocity probability density function of the shale particles with or without antistatic agents.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2016-08-11
    Description: Author(s): Wang Yang, Yi Li, and Congjun Wu We systematically generalize the exotic He 3 − B phase, which not only exhibits unconventional symmetry but is also isotropic and topologically nontrivial, to arbitrary partial-wave channels with multicomponent fermions. The concrete example with four-component fermions is illustrated including the iso… [Phys. Rev. Lett. 117, 075301] Published Wed Aug 10, 2016
    Keywords: Condensed Matter: Structure, etc.
    Print ISSN: 0031-9007
    Electronic ISSN: 1079-7114
    Topics: Physics
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  • 4
    Publication Date: 2019-07-13
    Description: We present and discuss ultraviolet and optical photometry from the Ultraviolet/Optical Telescope, X-ray limits from the X-Ray Telescope on Swift, and imaging polarimetry and ultraviolet/optical spectroscopy with the Hubble Space Telescope, all from observations of ASASSN-15lh. It has been classified as a hydrogen-poor superluminous supernova (SLSN I), making it more luminous than any other supernova observed. ASASSN-15lh is not detected in the X-rays in individual or co-added observations. From the polarimetry we determine that the explosion was only mildly asymmetric. We find the flux of ASASSN-15lh to increase strongly into the ultraviolet, with an ultraviolet luminosity 100 times greater than the hydrogen-rich, ultraviolet-bright SLSN II SN2008es. We find that objects as bright as ASASSN-15lh are easily detectable beyond redshifts of 4 with the single-visit depths planned for the Large Synoptic Survey Telescope. Deep near-infrared surveys could detect such objects past a redshift of 20, enabling a probe of the earliest star formation. A late rebrightening-most prominent at shorter wavelengths -is seen about two months after the peak brightness, which is itself as bright as an SLSN. The ultraviolet spectra during the rebrightening are dominated by the continuum without the broad absorption or emission lines seen in SLSNe or tidal disruption events (TDEs) and the early optical spectra of ASASSN-15lh. Our spectra show no strong hydrogen emission, showing only Ly absorption near the redshift previously found by optical absorption lines of the presumed host. The properties of ASASSN-15lh are extreme when compared to either SLSNe or TDEs.
    Keywords: Earth Resources and Remote Sensing
    Type: GSFC-E-DAA-TN41819 , The Astrophysical Journal (ISSN 0004-637X) (e-ISSN 1538-4357); 828; 1; 3
    Format: text
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