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  • Chemical Engineering  (1)
  • Chemistry  (1)
  • Coupling agent  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of polymer research 4 (1997), S. 91-99 
    ISSN: 1572-8935
    Keywords: Polymer blend ; PA6 ; PPE ; Epoxy ; Reactive compatibilizer ; Coupling agent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A commercially available multi-functional epoxy monomer, phenolic novolac epoxy (PNE) resin, has demonstrated to be an effective reactive compatibilizer for the blends of polyamide-6 (PA6) and poly(2,6-dimethyl-1,4-phenylene ether) (PPE). It requires about 1/10 by weight relative to a typical conventional reactive compatibilizer to achieve same level of compatibilization in terms of mechanical property improvements. By acting as a coupler, this multi-functional epoxy can react with PA6 and PPE during melt blending and produces the desirable PA6-co-PNE-co-PPE mixed copolymers at the interface. This in situ-formed copolymer containing PA6 and PPE segments tends to reside at the interface between PA6 and PPE domains to reduce melt interfacial tension and enhance interface adhesion as an efficient compatibilizer of the PA6/PPE blends.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The polyurethane protective surface material, which were made from four different types of polyester and polyether polyol, have been studied with respect to their ultimate properties. The PTMG (polyoxytetramethylene glycol)- and PPG (polyoxypropylene giyco)-based polyurethane protective surface materials exhibited the best results. Use of JIPNs (joint interpenetrating polymer networks), prepared from combinations of polyurethnes with an epoxy adduct with coupling agents and talc, could clearly improve the adhesive strength resistance to water in negative pressure cavitation erosion (by determination with a rotating dish apparatus) and the adhesive strength resistance toward boiling water. The polyurethane protective surface material, which was composed of three separated layers, showed better resistance to cavitation erosion than an epoxy system, poly(methyl methacrylate), aluminum, steel, and different alloys in tests using the venturi tube and the rotating dish apparatus for simulated cavitation erosion, as well as in some power stations in actual field trials.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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