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  • Articles  (3)
  • Polymer and Materials Science  (3)
  • Cell & Developmental Biology
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (3)
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  • Articles  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 2587-2589 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1585-1600 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Linear viscoelastic properties are found to be a sensitive measure of flow-induced structural changes in a block copolymer. Styrene-butadiene-styrene block copolymer (SBS) with 26% polystyrene (PS) forms a macrostructure in the quiescent state with grains of the order of 1-10 μm. Within each grain, phase separation gives rise to a regular two-phase microstructure with cylindrical PS domains with radius of the order of 200 Å. Large-amplitude oscillatory shear (γ = 4.5) at temperatures between 139 and 181°C was applied to after the grain structure with the objectives of removing the discontinuities at the grain boundaries and of aligning the domains into a continuous ultrastructure. The SBS behaved like a solid (tan δ 〈 1 at low ω) before and like a liquid (tan δ 〉 1) after shear modification. This change expressed itself in the removal of the long relaxation times from the linear viscoelastic spectrum; the intermediate and low relaxation times were not affected by the shear modification. The viscoelastic spectrum slowly recovered during annealing with recovery times of the order of the longest relaxation time of the quiescent structure. Birefringence studies showed that the SBS did not recover into its original grain structure but into a highly oriented domain structure. The discontinuities at the grain boundaries could not be removed completely.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 231-240 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The benefits obtained from the addition of small quantities of chlorinated polyolefins to paving grade asphalt binders were investigated. A chlorinated polyethylene plastomer, Tyrin 2552, and a chlorinated olefinic elastomer, Tyrin CM0730, were added to asphalt binders at 3 and 5 wt % and subsequently reactively processed to facilitate compatibilization. The mixtures were analyzed for rheological performance relating to fatigue and rutting as well as low-temperature fracture performance. The addition of small quantities of these polymers to the asphalt binders resulted in significant improvements over conventional modifiers at both the high and low temperature extremes. © 1994 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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