ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Lithium batteries are attractive for energy storage because of their high theoretical energy densities. A mechanism of an electrochemical intercalation reaction is suggested for the discharge of the first Li-fullerenated poly(N-vinylcarbazole) battery on the basis of experimental data obtained from cyclic voltammetry, FTIR, XRD, and ESR. The above battery has a higher open-circuit voltage (ca. 3.2 V), and its discharge may be ascribed to the electrochemical interacalation process of lithium in fullerenated poly(N-vinylcarbazole) for positive electrode materials. The effect of the discharge of the electric cell on the structure and paramagnetic property of fullerenated poly(N-vinylcarbazole) is discussed. © 1996 John Wiley Sons, Inc.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
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