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  • Articles  (7)
  • Inorganic Chemistry  (3)
  • Bombyx mori  (2)
  • Calcium ions  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Schiff Base Complexes of Rhodium(I) with Tridentate N-Methyl-S-methyldithiocarbazate Ligands NCL Communication No. 3827. (1986)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 536 (1986), S. 173-178 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Schiffsche Basen-Komplexe des Rhodium(I) mit dreizähnigen N-Methyl-S-methyldithiocarbazat-LigandenSchiffsche Basen aus der Kondensation von β-Diketonen mit N-Methyl-S-methyl-dithiocarbazaten ergeben bei Reaktion mit [Rh(μ-Cl)(CO)2]2 cis-Dicarbonyl-Komplexe Rh(CO)2(Schiff). Die aus aromatischen Aldehyden erhaltenen bilden trans-Dicarbonyl-Komplexe. Mit einem Überschuß von Triphenylphosphin ergeben diese Komplexe nur Rh(CO)(PPh3)(Schiff). Cis-1,5-cyclooctadien (COD) reagiert mit cis-Dicarbonyl-Komplexen zu carbonylfreien Produkten Rh(COD)(Schiff); gleiche Reaktionen wurden bei trans-Dicarbonyl-Komplexen beobachtet. Oxydative Addition von Brom an diese Komplexe ergibt Dibromderivate, in denen die Schiffsche Base als zweizähniger Ligand wirkt, Rh(PPH3)2(Schiff)-Komplexe wurden durch Reaktion oben genannter Schiffscher Basen mit Rh(PPh3)3Cl erhalten. Die Strukturen dieser neuen Komplexe wurden auf Grund von IR-und 1H-NMR-Spektren bestimmt.
    Notes: Schiff bases derived from the condensation of β-diketones with N-methyl-S-methyldithiocarbazates yield cis dicarbonyl complexes Rh(CO)2 (Schiff) on reaction with [Rh(μ-Cl)(CO)2]2. Those derived from aromatic aldehydes form trans dicarbonyl complexes. These complexes with excess of triphenylphosphine give only Rh(CO)(PPh3)(Schiff). cis-1,5-cyclooctadiene (COD) reacts with cis dicarbonyl complexes to yield the carbonyl-free product Rh(COD)(Schiff); similar reactions have not been observed in the case of trans-dicarbonyl complexes. Oxidative addition of bromine to these complexes yields dibromo derivative in which the Schiff base acts as bidentate chelate. Rh(PPh3)2(Schiff) complexes have been obtained from the reaction of above Schiff bases with Rh(PPh3)3Cl. The structures of these new complexes have been determined based on IR and 1H NMR spectra.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19865360520
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  • 2
    Electronic Resource
    Electronic Resource
    Novel chelated compounds of Bis-β-carbomethoxyethltin(IV) (1980)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 465 (1980), S. 204-208 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Neue Chelate des Bis-β- Carbomethoxyethlzinn(IV)Zwei- und dreizähnige Chelatinganden (s. Abstract) Können die Chloratome des Bis-β-carbomethoxethyldichlozinn(IV) unter Bildung neuer stabiler Chelatverbindungen ersetzen. Bromierung dieser Verbindungen unter milden Bedingungen zeigt, daß die Chelatinganden bevorzugt abgespalten werden. Die neun Verbindungen werden durch Elementaranalyse, IR- und PMR-Spektren sowie Molekulargewichtsbestimmungen Charakterisiert und mögliche Strukturen werden Vorgeschlagen.
    Notes: Bi- and tri-denate Chelating ligands (acetylacetone, salicylasehyde, 8-hydroxy quinoline, dibenzoylmethane, benzoyl phenhydroxlmanine, 2-hydroxy benzophenone, 2-hydroxy 4-methoxy benzophenone and salichyaldine) replace cholrine atoms of bis-β-carbomethoxyethyl dischlorotin (IV) to form new stable Cheleted compounds. Bromination studies under mild conditions indicate that in these compounds the Cheleated ligand part is preferentially cleaved. The new compounds are characterized by elemental analysis. IR and PMR spectra and molecular weight, and possible structures have been assigned.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19804650124
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  • 3
    Electronic Resource
    Electronic Resource
    Cationic Ruthenium(II) Carbonyl Complexes with Nitrile LigandsNCL Communication No. 3625. (1985)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 527 (1985), S. 203-207 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Kationische Carbonyl-Ruthenium(II)-Komplexe mit Nitril-LigandenStabile kationische Komplexe vom Typ [RuCO(PPh3)2(L)RCN]+[ClO4]-, mit Acetonitril bzw. Acrylonitril wurden dargestellt. Als zweizähnige Liganden (LH) dienten Acetylaceton, Benzoylaceton, Dibenzoylmethan, Trifluorothenoylaceton und 8-Hydroxochinolin. Die Komplexe wurden analysiert, ferner durch IR-, 1H- und 31P-NMR-, Leitfähigkeits- und ESCA-Messungen charakterisiert; eine Stereochemie erscheint möglich.
    Notes: Stable cationic complexes of the type [RuCO(PPh3)2(L)(RCN)]+[ClO4]- derived from acetonitrile and acrylonitrile have been synthesized. The bidentate ligands (LH) used are acetylacetone, benzoylacetone, dibenzoylmethane, trifluorothenoyl acetone and 8-hydroxyquinoline. The complexes have been characterized by elemental analysis, IR, conductivity, 1H and 31P NMR and ESCA studies, and possible stereochemistry has been established.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19855270823
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  • 4
    Electronic Resource
    Electronic Resource
    Differential transcription of multiple copies of a silk worm gene encoding tRNA"1^G^l^y
    Amsterdam : Elsevier
    Gene 134 (1993), S. 183-190 
    Details
    ISSN: 0378-1119
    Keywords: Bombyx mori ; RNA polymerase III transcription ; gene family ; negative regulation ; positive regulation ; regulatory elements ; tissue specificity ; transcription factors ; transcription regulation
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0378-1119(93)90092-H
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  • 5
    Electronic Resource
    Electronic Resource
    Determination of trace amounts of 5-methylcytosine in DNA by reverse-phase high-performance liquid chromatography
    Amsterdam : Elsevier
    Analytical Biochemistry 164 (1987), S. 164-169 
    Details
    ISSN: 0003-2697
    Keywords: 5-methylcytosine ; Bombyx mori ; Drosophila melanogaster ; HPLC techniques ; trace analysis
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1016/0003-2697(87)90381-2
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  • 6
    Electronic Resource
    Electronic Resource
    Requirement for calcium ions in mycobacteriophage I3 DNA injection and propagation (1980)
    Springer
    Archives of microbiology 124 (1980), S. 249-254 
    Details
    ISSN: 1432-072X
    Keywords: Calcium ions ; Phage propagation ; Phage DNA injection ; Mycobacteriophage 13
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Ca2+ ions are absolutely necessary for the propagation of mycobacteriophage I3 in synthetic medium. These ions are required for successful infection of the host and during the entire span of the intracellular development of the phage. A direct assay of the phage DNA injection using 32[P] labelled phage, showns that Ca2+ ions are necessary for the injection process. The injection itself is a slow process and takes 15 min to complete at 37°C. The bacteria infected in presence of Ca2+ tend to abort if the ions are subsequently withdrawn from the growth medium. The effect of calcium withdrawal is maximally felt during the early part of the latent period; however, later supplementation of Ca2+ ions salvage phage production and the mature phage progeny appear after a delayed interval, proportional to the time of addition of Ca2+.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00427734
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  • 7
    Electronic Resource
    Electronic Resource
    Localization of calcium in murine epidermis following disruption and repair of the permeability barrier (1992)
    Springer
    Cell & tissue research 270 (1992), S. 503-512 
    Details
    ISSN: 1432-0878
    Keywords: Epidermis ; Permeability ; Calcium ions ; Ionic localization ; Mouse (hr/hr)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Perturbation of the cutaneous permeability barrier results in rapid secretion of epidermal lamellar bodies, and synthesis and secretion of new lamellar bodies leading to barrier repair. Since external Ca2+ significantly impedes the repair response, we applied ion capture cytochemistry to localize Ca2+ in murine epidermis following barrier disruption. In controls, the numbers of Ca2+ precipitates in the basal layer were small, increasing suprabasally and reaching the highest density in the stratum granulosum. Barrier disruption with acetone produced an immediate, marked decrease in Ca2+ in the stratum granulosum, accompanied by secretion of lamellar bodies. Loss of this pattern of Ca2+ distribution was associated with the appearance of large Ca2+ aggregates within the intercellular spaces of the stratum corneum. The Ca2+-containing precipitates progressively reappeared in parallel with barrier recovery over 24 h. Disruption of the barrier with tape stripping also resulted in loss of Ca2+ from the nucleated layers of the epidermis, but small foci persisted where the stratum corneum was not removed; in these sites the Ca2+ distribution did not change and accelerated secretion of lamellar bodies was not observed. Following acetone-induced barrier disruption and immersion in isoosmolar sucrose, the epidermal Ca2+ gradient did not return, and both lamellar body secretion and barrier recovery occurred. However, with immersion in isoosmolar sucrose plus Ca2+, the epidermal Ca2+ reservoir was replenished, and both secretion of lamellar bodies and barrier recovery were impeded. These results demonstrate that barrier disruption results in loss of the epidermal Ca2+ reservoir, which may be the signal that initiates lamellar body secretion leading to barrier repair.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00645052
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