ISSN:
0935-6304
Keywords:
Gas chromatography
;
Capillary, glass
;
„bo“ data (starting peak width) in valveless multidimensional operation studied
;
Heart cutting, trapping, re-injection effects measured
;
Band broadening caused by connections small (160 ms2)
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In order to permit valveless MDSS operation and easy column change, the hardware designed contains several connections. These can give rise to extra-column band broadening effects. In order to quantitate such effects, the packed-capillary column configuration (without trap) was used. The band broadening caused by the connections was found to be small: 120 ms2. A more practical approach was used to check the performance of the trap (re-injection) in the capillary-trap-capillary column configuration. Here the results obtained with re-injection from the trap were compared with results obtained in transfer and heart-cutting modes while the trap was heated. Re-injection was tested with n-alkanes ranging from n-C6 to n-C28. A starting peak width of 1.6 s was found.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240020712
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