ISSN:
1434-1948
Keywords:
Ferrocenyl ligands
;
Electrochemistry
;
Fluorescence
;
Azaalkyl compounds
;
Crown compounds
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New azaalkyl or azacrown ferrocenyl compounds containing a C5H4COCC- linkage are accessible from mono- or diacetylferrocene upon treatment with the appropriate aldehydes (CHOC6H4-p-R, R = NEt2, N-aza-15-crown-5). Preliminary results concerning the electrochemical behaviour of complexes [(C5H5)Fe(C5H4COCH=CHC6H4NEt2)] (3a), [Fe(C5H4COCH=CHC6H4NEt2)2] (5a), the novel ferrocenophane [Fe(C5H4COCH2)2CHC6H4NEt2] (6a) and its protonated species [Fe(C5H4COCH2)2CHC6H4NHEt2][BF4] (7a), are reported. The ferrocenyl ligand 5a is a rare example of a molecule which is both electroactive and fluorescent.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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