ISSN:
1434-193X
Keywords:
Fullerenes
;
Cubanes
;
Atropisomerism
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New dumb-bell-type fullerene adducts 2, 4, and 8a-b could be synthesized via bifunctional nitrile oxides. The [60]fullerene derivative 16 of this type was synthesized by twofold esterification with an isoxazolo[60]fullerenecarboxylic acid derivative. In the latter case the reaction was used to link the archimedic polyhedron fullerene with the platonic element cubane. When a bulky spacer between the fullerene units was used, atropisomeres 8a-b occurred. The fullerene derivative 11 with an anthracene moiety exhibited axial chirality.
Type of Medium:
Electronic Resource
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