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  • Articles  (45)
  • Polymer and Materials Science  (40)
  • nanocomposites  (3)
  • permeation  (2)
  • sorption  (2)
  • Atomic, Molecular, and Optical Physics  (1)
  • Instable interface  (1)
  • Nickel coated graphite  (1)
  • 1
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    New Class of Three-Body States (2012)
    American Physical Society (APS)
    Details
    Publication Date: 2012-05-23
    Description: Author(s): Nicolais L. Guevara, Yujun Wang, and B. D. Esry We calculate the three-body spectrum for identical bosons interacting via attractive 1/ r 2 potentials. We find an infinite number of three-body states even when the pair interactions are too weak to support any two-body states. These new states thus share this surprising scenario with the Efimov effe... [Phys. Rev. Lett. 108, 213202] Published Tue May 22, 2012
    Keywords: Atomic, Molecular, and Optical Physics
    Print ISSN: 0031-9007
    Electronic ISSN: 1079-7114
    Topics: Physics
    Published by American Physical Society (APS)
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    PAPER CURRENT
  • 2
    Electronic Resource
    Electronic Resource
    Synthesis and characterization of new polymer-ceramic nanophase composite materials (1996)
    Springer
    Applied composite materials 3 (1996), S. 103-116 
    Details
    ISSN: 1573-4897
    Keywords: nanocomposites ; thin film ; spin-coater deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Optically transparent nanocomposites are of special interest since they have great potential in optical applications. The synthesis of poly(methacrylic methylester)/monodispersed Cu2(OH)2CO3 particles, a new nanocomposite material with a refractive index similar to glass, is here described. The system can be easily deposited on glass plates by spin-coating technology, yielding homogeneous, low-defect thin films of high transparency, that can be used as color filters for liquid crystal displays. Differential scanning calorimetry (DSC), dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), and energy dispersive spectroscopy (EDS) have been used to characterize the composite material.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00158996
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  • 3
    Electronic Resource
    Electronic Resource
    Stability of nickel coatings on carbon fiber preforms: A SEM investigation (1994)
    Springer
    Applied composite materials 1 (1994), S. 231-245 
    Details
    ISSN: 1573-4897
    Keywords: MMC ; Nickel coated graphite ; Squeeze casting ; Instable interface ; Electroplating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Metal Matrix Composites (MMC's) reinforced with continuous fibers were generally fabricated by a foil-sandwich technique or by liquid metal infiltration. Liquid metal infiltration may be used to cast final shapes in molds containing fiber preforms. It is also used to make composite wire from which may be fabricated panels and shapes by hot-press diffusion bonding or pultrusion. The major drawback of this method is that the molten matrix must wet the fiber for successful infiltration to occur, requiring special fiber surface treatments or matrix additives, and that, molten metals generally dissolve or degrade the fibers, necessitating a barrier coating on the fibers. All these problems can be solved using carbon fibers coated with metallic layers, e.g. nickel. This work analyses an easy method to produce modified carbon fibers by electroplating and the process of its recristallization. The topography of the growth front of the deposit has been studied. At temperatures higher than about 300° C an annealing under vacuum is required, because of the high reactivity of metal coating, nevertheless the heat treatment of metal deposit produces always an embrittled material.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00567529
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  • 4
    Electronic Resource
    Electronic Resource
    A method for the preparation of PMMA-SiO2 nanocomposites with high homogeneity (1996)
    Springer
    Applied composite materials 2 (1996), S. 385-393 
    Details
    ISSN: 1573-4897
    Keywords: nanocomposites ; poly(methyl methacrylate) ; silica
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract It is possible to optimize the performance of the inorganic-organic composites dispersing the inorganic component in the organic matrix on a nanomiter length scale. If dry the inorganic phase cannot be intimately dispersed during the incorporation in the matrix. When the particle surface is organically modified, and the incorporation is made starting from a liquid dispersion (particles in polymer solution), the resulting composites exhibit an excellent homogeneity. Here, monolithic [poly(methyl methacrylate)/monodisperse silica particles] nanocomposites have been prepared and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic light scattering (DLS), micro-hardness, and differential scanning calorimetry (DSC).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00564575
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  • 5
    Electronic Resource
    Electronic Resource
    Fractal Analysis and Simulation of Surface Roughness of Ceramic Particles for Composite Materials (1997)
    Springer
    Applied composite materials 4 (1997), S. 69-81 
    Details
    ISSN: 1573-4897
    Keywords: nanocomposites ; roughness ; fractal dimension
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An analytical model is presented for the determination of the fractal dimensions of particles which are widely used as reinforcement in nanocomposites. The model is used to characterize the surface irregularity or roughness. It was found that fractal dimensions of both the contour and surface of particles depend only on the relative particles size ratio between secondary particles and subunits. It is proposed that, in practical applications, the fractal dimension of a certain reinforcement particle can be obtained by a combination of this model and a state-of-the-art instrument that can determine the sizes of primary and secondary particles by image analysis. It is possible to relate the fractal dimension with the adhesion and other physical and chemical properties at the interface between particles and matrix.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1008824606064
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  • 6
    Electronic Resource
    Electronic Resource
    Viscosity of bead suspensions in polymeric solutions (1974)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 2809-2818 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Viscosity measurements made by a cone-plate viscometer on polyisobutylene in decalin solutions at different concentrations and their corresponding glass bead suspensions with filler loadings up to 40% by volume are reported. The range of shear rate $ \dot \gamma $ investigated is between 0.1 and 1000 sec-1. The solutions show shear-thinning behavior, and the relative viscosity ηr of the slurries generally decreases with increasing shear rate. The results indicate two different types of mechanism, respectively at high and low shear rates. At low $ \dot \gamma $, the relative viscosity can be correlated extending relations already well known for suspensions in Newtonian liquids which are based on the mechanism of aggregate disruption. The behavior at high $ \dot \gamma $ values is believed to be due to the influence of the filler on the flow properties of macromolecules, in particular on relaxation time. Through a shifting procedure, an increase in relaxation time which depends on filler content and not on polymer concentration is shown.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1974.070180922
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  • 7
    Electronic Resource
    Electronic Resource
    Calorimetric quality control of UV cured optical fiber-coatings (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 2077-2086 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The application of ultraviolet (UV)-curable polymeric coatings provides optical fibers with improved strength, microbending resistance, and long-term durability. To ensure constant optical properties of the glass fibers during their life, fully polymerized coatings are needed. Test methods capable of determining the degree of cure and the consistency of the polymeric materials used are therefore required by the fiber technology. This investigation deals with the description of a calorimetric test method for the direct determination of the prepolymer reactivity and its final degree of cure. The analytical technique uses a modified differential scanning calorimeter (DSC) capable of direct measurements of heat fluxes generated during the UV-activated polymerization of photoinitiated acrylic prepolymers. Finally, the degree of cure and the glass transition temperatures were determined for the polymerized coating also in presence of sorbed moisture.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070330619
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  • 8
    Electronic Resource
    Electronic Resource
    Water sorption kinetics in poly(aryl ether ether ketone) (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 381-392 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of diffusion of water from different activity vapors and liquid phase have been investigated in glassy amorphous poly(aryl ether ether ketcne) (PEEK) films at the temperature of 60°C and in glassy semicrystalline PEEK sheets at different temperatures, respectively. In the case of the amorphous PEEK films (250 μm thick) the data at low activity levels were interpreted by means of a purely Fickian mechanism. At higher activity levels the material has shown the presence of a relaxation process; in this case the data have been interpreted using a model proposed by Berens and Hopfenberg. Equilibrium sorption isotherm is also reported. Liquid water sorption in semicrystalline (30%) PEEK sheets (2 mm thick) has been determined to follow the classical Fickian mechanism. The water uptake values obtained for both amorphous and semicrystalline PEEK, confirm the good moisture and liquid water resistance of this kind of high performance thermoplastic polymer.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070370207
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  • 9
    Electronic Resource
    Electronic Resource
    CO2 sorption in uniaxially drawn atactic polystyrene (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 1805-1812 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The CO2 solubility in oriented and unoriented atactic polystyrene films has been investigated. Orientation does not change the nature of the sorption process; however, it decreases the level of solubility. Both the Langumir sorption term and the Henry's-law contribution are affected by orientation. The decrease of solubility is correlated with an increase of density due to orientation. A simple experiment has been described to evaluate the depression of the glass transition temperature of polystyrene containing dissolved carbon dioxide.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1986.090240815
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  • 10
    Electronic Resource
    Electronic Resource
    Water transport in a polyketone terpolymer (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 1365-1370 
    Details
    ISSN: 0887-6266
    Keywords: polyketone terpolymer ; water vapor ; permeation ; clustering ; sorption ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Water transport in a polyketone terpolymer was analyzed performing both sorption and permeation experiments. Water vapor sorption tests were conducted at four temperatures (35, 45, 55, and 65°C) and at several activities. The analysis of sorption isotherms revealed the occurrence of water clustering. A reduction of the endothermicity of mixing as the amount of sorbed water increased was observed which is consistent with significant association of penetrant molecules in the polymer. Permeation experiments performed at 35°C at upstream pressures ranging from 4 to 25 Torr showed evidence of a reduction in water diffusivity as function of sorbed water concentration which is a typical indication of penetrant aggregation. © 1995 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1995.090330906
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