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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 26 (2013): 8476–8494, doi:10.1175/JCLI-D-12-00860.1.
    Description: Characteristics of atmospheric blocking in the Southern Hemisphere (SH) are explored in atmospheric general circulation model (AGCM) simulations with the Community Atmosphere Model, version 3, with a particular focus on the Australia–New Zealand sector. Preferred locations of blocking in SH observations and the associated seasonal cycle are well represented in the AGCM simulations, but the observed magnitude of blocking is underestimated throughout the year, particularly in late winter and spring. This is related to overly zonal flow due to an enhanced meridional pressure gradient in the model, which results in a decreased amplitude of the longwave trough/ridge pattern. A range of AGCM sensitivity experiments explores the effect on SH blocking of tropical heating, midlatitude sea surface temperatures, and land–sea temperature gradients created over the Australian continent during austral winter. The combined effects of tropical heating and extratropical temperature gradients are further explored in a configuration that is favorable for blocking in the Australia–New Zealand sector with warm SST anomalies to the north of Australia, cold to the southwest of Australia, warm to the southeast, and cool Australian land temperatures. The blocking-favorable configuration indicates a significant strengthening of the subtropical jet and a reduction in midlatitude flow, which results from changes in the thermal wind. While these overall changes in mean climate, predominantly forced by the tropical heating, enhance blocking activity, the magnitude of atmospheric blocking compared to observations is still underestimated. The blocking-unfavorable configuration with surface forcing anomalies of opposite sign results in a weakening subtropical jet, enhanced midlatitude flow, and significantly reduced blocking.
    Description: C.C.U. received support from the Australian Research Council through funding awarded to the Centre of Excellence for Climate System Science and the Penzance Endowed Fund at WHOI. P.C.M., M.J.P., and J.S.R. were funded by the CSIRO Climate Adaptation Flagship and the Managing Climate Variability R&D Program.
    Description: 2014-05-01
    Keywords: Australia ; Southern Hemisphere ; Atmosphere-ocean interaction ; Atmospheric circulation ; Blocking ; General circulation models
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 28 (2015): 8289–8318, doi:10.1175/JCLI-D-14-00555.1.
    Description: This study quantifies mean annual and monthly fluxes of Earth’s water cycle over continents and ocean basins during the first decade of the millennium. To the extent possible, the flux estimates are based on satellite measurements first and data-integrating models second. A careful accounting of uncertainty in the estimates is included. It is applied within a routine that enforces multiple water and energy budget constraints simultaneously in a variational framework in order to produce objectively determined optimized flux estimates. In the majority of cases, the observed annual surface and atmospheric water budgets over the continents and oceans close with much less than 10% residual. Observed residuals and optimized uncertainty estimates are considerably larger for monthly surface and atmospheric water budget closure, often nearing or exceeding 20% in North America, Eurasia, Australia and neighboring islands, and the Arctic and South Atlantic Oceans. The residuals in South America and Africa tend to be smaller, possibly because cold land processes are negligible. Fluxes were poorly observed over the Arctic Ocean, certain seas, Antarctica, and the Australasian and Indonesian islands, leading to reliance on atmospheric analysis estimates. Many of the satellite systems that contributed data have been or will soon be lost or replaced. Models that integrate ground-based and remote observations will be critical for ameliorating gaps and discontinuities in the data records caused by these transitions. Continued development of such models is essential for maximizing the value of the observations. Next-generation observing systems are the best hope for significantly improving global water budget accounting.
    Description: This research was funded by multiple grants from NASA’s Energy and Water Cycle Study (NEWS) program.
    Description: 2016-05-01
    Keywords: Physical Meteorology and Climatology ; Water budget ; Observational techniques and algorithms ; Remote sensing ; Mathematical and statistical techniques ; Numerical analysis/modeling
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 15 (1976), S. 1873-1875 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 14 (1970), S. 1093-1101 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The reaction of phenyl isocyanate with phthalic anhydride to form N-phenylphthalimide is strongly solvent dependent and catalyzed by tertiary amines. Water and alcohol promote imide formation, but Lewis acids and organometallic compounds are ineffective. In DMSO solvent, benzophenone tetracarboxylic dianhydride (BTDA) and polymethylene polyphenol isocyanate (PAPI) polymerize with the evolution of carbon dioxide to yield a foamed polyimide. The solvent-freed open-celled foams exhibit exceptional fire resistance and thermal stability.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 6 (1968), S. 1887-1902 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The steady-flow behavior of five samples of branched poly(vinyl acetate) has been studied with the Weissenberg rheogoniometer. The branching densities and molecular weight distributions were known from an analysis of the polymerization kinetics. Measurements were made on concentrated diethyl phthalate solutions (0.170 and 0.225 g/ml) at temperatures of 30 and 70°C. The viscosities of all solutions at zero shear rate were less than of solutions of linear poly(vinyl acetate) with the same weight-average molecular weight. The amount of decrease was in excellent agreement with Bueche's theory of melt viscosity in branched systems. The viscosity versus shear rate curves were surprisingly independent of molecular weight distribution, the data from all samples being superimposable on the same master curve. Relaxation times derived independently from the viscosity behavior and the normal stress data were of similar magnitude and always close to the Rouse relaxation time of each solution.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Optical rotatory dispersion studies have been carried out at temperatures up to 150 °C. on poly(γ-benzyl L-glutamate) in α-chloronaphthalene and N-methylcaprolactam, and on poly-ε-carbobenzoxy-L-lysine, poly-δ-carbobenzoxy-L-ornithine, and poly(L-glutamic acid) in N-methylacetamide. The Moffitt-Yang -b0 values were large in all cases, but significant decreases in -b0 were observed at the upper temperature limits of the study suggesting that a transition region was being entered. Polymer degradation generally precluded examination of the systems through the suggested transition region.
    Additional Material: 2 Ill.
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  • 7
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyamino acids which are soluble and helical in acetic acid and dichloroacetic acid (DCA) have been observed to undergo a helix to random chain transition upon the addition of lithium salts of strong acids. The transition can be reversed by diluting the salt. Apparently only lithium cations are able to bring about the polycarbobenzoxy-L-lysine (PCBL) transition in acetic acid, whereas the anions display a varying degree of effectiveness; ClO4- 〉 Br- 〉 TSA- 〉 Cl- 〉 NO3-. The lithium salts of carboxylate anions such as OAc- and TFA- do not cause polymer unwinding in acetic acid. Neither do the acids, TSA, HCl, TFA, or DCA induce the transformation in acetic acid. Poly-L-alanine (PLA) in DCA unfolds as LiBr is added, but does not unfold in the presence of 0.5M (CH3)4NBr, 0.25M CsBr, or 0.32M HCl. These results are explained on the basis of a direct interaction of the lithium salt with the polymer amide groups to form an ion-pair complex. The extent to which the union of the ion pair can dissociate from the complex in the low dielectric constant, environment determines the degree of unfolding of the polymer. The anion dissociation equilibrium presumably therefore would lie in the same order as given above. Acids such as HCl and TSA are considered to substantially protonate and ion-pair with the polymer, but do not readily dissociate the anion partner from the complex, and therefore do not produce an unstable positively charged helical structure.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 8 (1969), S. 433-448 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The folding of randomly coiled poly(L-glutamic acid) to the helical state has been studied in N-methylacetamide by titration methods. Since this solvent would be expected to form amide-peptide group hydrogen bonds with the unfolded form of the polymer, to a first approximation no helix stabilization could come from intrapolymer hydrogen bonds. The titration data, collected from 30 to 70°C yield the following values per residue for the thermodynamic parameters governing the coil-helix reaction for the uncharged polymer: ΔG30°C°, -1. 9 ± 0.1 kcal; Δ H°, 0 ± 0.1 kcal; ΔS30°C°, 6.3 ± 0.6 eu. In N-methyl acetamide, the helix is an order of magnitude more stable than in water, and this stabilization appears to be entirely the result of the entropy gained by solvent molecules which are released from the polymer upon folding.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 221-227 
    ISSN: 0887-6266
    Keywords: interfacial tension ; thermotropic ; copolyester ; polyether sulphone ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Due to the increasing interest in forming blends of liquid-crystalline polymers with conventional thermoplastics, it becomes important to determine the interfacial tension between two such polymers. A method for evaluating the interfacial tension between a thermotropic copolyester based on hydroxybenzoic and hydroxynaphthoic acid residues, and polyethersulfone is presented, based on the Fort and Patterson method. It is found that the value of the interfacial tension in the melt is much higher than is the case between conventional polymer pairs. It is suggested that this high value reflects an entropic effect due to the strong exclusion of the flexible coil polymer from the nematic melt. © 1993 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 215-227 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copolyamides of nylon 6,6 with bis(2-carboxyethyl)methylphosphine oxide (CEMPO) were prepared by melt polycondensation of nylon 6,6 salt with CEMPO and hexamethylene diamine. The effect of CEMPO upon melting point, moisture regain, boiling water shrinkage, water wicking, tensile properties, thermal stability, static dissipation, and flammability of nylon 6,6 fibers and fabrics was determined. The fiber properties were greatly affected by the high water absorption and solubility characteristics of the phosphine oxide linkage. However, crystallinity and orientation were not greatly disturbed by up to 30-40M% CEMPO substitution in nylon 6,6. The copolyamides were of improved flame resistance compared to nylon 6,6 and were also found to give improved flame resistance in blends of the copolymer with various commercial plastics. In addition, CEMPO and the corresponding diamine, bis(3-aminopropyl)methylphosphine oxide were used to prepare a series of cycloaliphatic and aromatic ring-containing polyamides, but problems were encountered with moisture sensitivity and low melting points with some of these polymers.
    Additional Material: 8 Ill.
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