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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 26 (2013): 8476–8494, doi:10.1175/JCLI-D-12-00860.1.
    Description: Characteristics of atmospheric blocking in the Southern Hemisphere (SH) are explored in atmospheric general circulation model (AGCM) simulations with the Community Atmosphere Model, version 3, with a particular focus on the Australia–New Zealand sector. Preferred locations of blocking in SH observations and the associated seasonal cycle are well represented in the AGCM simulations, but the observed magnitude of blocking is underestimated throughout the year, particularly in late winter and spring. This is related to overly zonal flow due to an enhanced meridional pressure gradient in the model, which results in a decreased amplitude of the longwave trough/ridge pattern. A range of AGCM sensitivity experiments explores the effect on SH blocking of tropical heating, midlatitude sea surface temperatures, and land–sea temperature gradients created over the Australian continent during austral winter. The combined effects of tropical heating and extratropical temperature gradients are further explored in a configuration that is favorable for blocking in the Australia–New Zealand sector with warm SST anomalies to the north of Australia, cold to the southwest of Australia, warm to the southeast, and cool Australian land temperatures. The blocking-favorable configuration indicates a significant strengthening of the subtropical jet and a reduction in midlatitude flow, which results from changes in the thermal wind. While these overall changes in mean climate, predominantly forced by the tropical heating, enhance blocking activity, the magnitude of atmospheric blocking compared to observations is still underestimated. The blocking-unfavorable configuration with surface forcing anomalies of opposite sign results in a weakening subtropical jet, enhanced midlatitude flow, and significantly reduced blocking.
    Description: C.C.U. received support from the Australian Research Council through funding awarded to the Centre of Excellence for Climate System Science and the Penzance Endowed Fund at WHOI. P.C.M., M.J.P., and J.S.R. were funded by the CSIRO Climate Adaptation Flagship and the Managing Climate Variability R&D Program.
    Description: 2014-05-01
    Keywords: Australia ; Southern Hemisphere ; Atmosphere-ocean interaction ; Atmospheric circulation ; Blocking ; General circulation models
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 28 (2015): 8289–8318, doi:10.1175/JCLI-D-14-00555.1.
    Description: This study quantifies mean annual and monthly fluxes of Earth’s water cycle over continents and ocean basins during the first decade of the millennium. To the extent possible, the flux estimates are based on satellite measurements first and data-integrating models second. A careful accounting of uncertainty in the estimates is included. It is applied within a routine that enforces multiple water and energy budget constraints simultaneously in a variational framework in order to produce objectively determined optimized flux estimates. In the majority of cases, the observed annual surface and atmospheric water budgets over the continents and oceans close with much less than 10% residual. Observed residuals and optimized uncertainty estimates are considerably larger for monthly surface and atmospheric water budget closure, often nearing or exceeding 20% in North America, Eurasia, Australia and neighboring islands, and the Arctic and South Atlantic Oceans. The residuals in South America and Africa tend to be smaller, possibly because cold land processes are negligible. Fluxes were poorly observed over the Arctic Ocean, certain seas, Antarctica, and the Australasian and Indonesian islands, leading to reliance on atmospheric analysis estimates. Many of the satellite systems that contributed data have been or will soon be lost or replaced. Models that integrate ground-based and remote observations will be critical for ameliorating gaps and discontinuities in the data records caused by these transitions. Continued development of such models is essential for maximizing the value of the observations. Next-generation observing systems are the best hope for significantly improving global water budget accounting.
    Description: This research was funded by multiple grants from NASA’s Energy and Water Cycle Study (NEWS) program.
    Description: 2016-05-01
    Keywords: Physical Meteorology and Climatology ; Water budget ; Observational techniques and algorithms ; Remote sensing ; Mathematical and statistical techniques ; Numerical analysis/modeling
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 6 (1968), S. 1887-1902 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The steady-flow behavior of five samples of branched poly(vinyl acetate) has been studied with the Weissenberg rheogoniometer. The branching densities and molecular weight distributions were known from an analysis of the polymerization kinetics. Measurements were made on concentrated diethyl phthalate solutions (0.170 and 0.225 g/ml) at temperatures of 30 and 70°C. The viscosities of all solutions at zero shear rate were less than of solutions of linear poly(vinyl acetate) with the same weight-average molecular weight. The amount of decrease was in excellent agreement with Bueche's theory of melt viscosity in branched systems. The viscosity versus shear rate curves were surprisingly independent of molecular weight distribution, the data from all samples being superimposable on the same master curve. Relaxation times derived independently from the viscosity behavior and the normal stress data were of similar magnitude and always close to the Rouse relaxation time of each solution.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 2005-2016 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyamides were prepared from linear, aliphatic dicarboxylic acids of six to twelve carbon atoms with 1,4-cyclohexanebis(methylamine), 1,4-cyclohexanebis (ethylamine), p-xylylenediamine, and p-phenylenebis(ethylamine). Melting points, glass transition temperatures, densities, and moisture regains were compared for the polymers to determine the relative effect of the cyclohexylene and phenylene linkages. While polyamides containing the trans-cyclohexylene group possessed higher glass transition temperatures than their aromatic counterparts, melting behavior was not as consistent. The odd-even rule, which states that polyamides with an even number of methylene linkages between the ring and the functional group melt higher than those with an odd number of such linkages, was violated in the cycloaliphatic systems. The Tg of ring-containing polyamide fibers was not dependent solely upon ring concentration, but was influenced by the molecular fit of the ringed intermediate in the polymer chains. Molecular fit appears to affect the Tg and melting point of alicyclic polyamides to a greater extent than the aromatic analogs. Differences in Tg, both within and among the polymer series, was not explained by either density or the degree of crystallinity.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 1867-1869 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2901-2904 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copoly(4,4′-oxanilideterephthalamide - 4,4′-phenyleneterephthalamide) (A-202/PPD) was synthesized by reaction of 4,4′-diaminooxanilide, p-phenylenediamine, and terephthaloyl chloride in organic solvents. Copolymer inherent viscosities in H2SO4 as high as 10.3 were obtained. Isotropic copolymer solutions (4% - 5% concentration) of A-202/40%-80% PPD were spun to fibers with tenacity/elongation/modulus at 1% extension in the 13-14 gpd/1.5%-2%/700-1000 gpd range. Oxamide and amide stabilities in 98-100% H2SO4 and 20% oleum were compared. Poly(4,4′-oxanilideterephthalamide) (A-202), A-202/PPD copolymers, and poly(4,4′-phenyleneterephthalamide) (PPT) were unstable in 20% oleum, but all proved relatively stable in 100% H2SO4. However, the oxamide linkage proved less stable than the amide linkage in 98% H2SO4. A-202 and A-202/PPD copolymers formed stable anisotropic spinning solutions in 1% oleum at 10-20% concentrations. Dynamic mechanical analyses (Vibron) showed no glass transition temperature (Tg) below 200°C. Dilatometric measurement of A-202/50% PPD revealed a Tg at 257°C. Differential thermal analyses of A-202/40-80% PPD exhibited endotherms at 470-480°C. Thermogravimetric analyses showed no significant weight loss below 400°C.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 8 (1970), S. 3089-3111 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several series of nylon 66 copolyamides were prepared with up to 30 mole-% substitution of ringed comonomers of the type X-(CH2)n-R-(CH2)n-X, where n = 0, 1, or 2; X = -NH2 or —CO2H; and R = phenylene, cyclohexylene, or naphthyle. The ring structure was correlated with glass transition temperature and melting point. The important features of ring structure fall into the following categories: ring isomerism, aromaticity, diamine vs. diacid substitution, chain length, and ring substitution. Proper “fit” (isomorphism) of the comonomer into the nylon 66 chain appears to be the main criterion for ringed copolymers of high Tg and high melting point.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 2195-2207 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolyamides of nylon 66 and 1,1,3-trimethyl-5-carboxy-3-(p-carboxyphenyl)indan (PIDA) were prepared by melt polycondensation of nylon 66 salt with PIDA in combination with hexamethylenediamine, trans-1,4-cyclohexanebis(methylamine), and m-xylylenediamine. In addition, hexamethylenediamine-PIDA was incorporated into the copolymer system of nylon 66-poly(hexamethylene terephthalamide). The effect of PIDA upon the intrinsic viscosity, crystallinity, density, melting point, moisture regain, tenacity, initial modulus, and the boiling-water shrinkage of such polyamides was determined. Particular emphasis was placed upon the influence of PIDA on the glass transition temperature of the polyamides. The effect of moisture on the glass transition temperature was also discussed. The physical properties of PIDA copolymers indicate that crystallinity virtually disappears above 20 mole-% PIDA concentration; however, the glass transition temperature measured at 0 and 30% RH increases sharply with increased PIDA concentration.
    Additional Material: 5 Ill.
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