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  • Astrophysics  (3)
  • Chemistry  (3)
  • CHEMISTRY  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 173-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 17 (1988), S. 113-119 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Blood glycoproteins containing terminal non-reducing D-galactosyl groups have previously been shown to be rapidly cleared from the circulatory system of animals. This occurs by interaction at the asialoglycoprotein receptor of the hepatocytes. We prepared several carbohydrate-insulin conjugates, containing one or more terminal D-galactosyl residues, to study their binding to this receptor. Fast atom bombardment (FAB) and 252Cf plasma desorption (PD) mass spectrometry were used to characterize the conjugates formed when insulin was treated with N-hydroxysuccinimide lactobionate. The synthetic approach, using N-hydroxysuccinimide amino acid esters, is a well-known procedure for peptide synthesis. However, the coupling reaction did not yield the expected lactobionyl insulin products. Instead, each lactobionyl group was accompained by an additional mass increment (115 daltons) in the conjugate structure. PD mass spectrometry verified that the products were intact modified insulins, while FAB mass spectrometry, with computerized peak matching and tandem mass spectrometry, provided the exact mass and structure of the additional mass increment. The two desorption ionization methods provided complementary data enabling the rapid characterization of these unexpected synthetic products.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Homopolymers and vinyl chloride copolymers have been prepared from the vinyl esters of mixed hydrogenated cyclized linolenic acid, 9,10-dichlorostearic acid, 9,10,12,13-tetrachlorostearic acid, 13,14-dichlorobehenic acid, 9(10)-phenylstearic acid and technical behenic acid. Vinyl 13,14-dichlorobehenate (29%)-vinyl chloride (71%) gave a copolymer with a brittle temperature of -2°C. All of the other copolymers with vinyl chloride had brittle temperatures of 16°C. or higher and behaved more like rigid plastics.
    Additional Material: 5 Tab.
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  • 4
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    In:  Other Sources
    Publication Date: 2011-08-16
    Description: Turbulent chemical reactions invariance preservation for zero diffusivity
    Keywords: CHEMISTRY
    Type: ; YSICA STATUS SOLIDI
    Format: text
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  • 5
    Publication Date: 2019-08-10
    Description: Departures of the energy spectrum of the cosmic microwave background (CMB) from a perfect blackbody probe a fundamental property of the universe - its thermal history. Current upper limits, dating back some 25 years, limit such spectral distortions to 50 parts per million and provide a foundation for the Hot Big Bang model of the early universe. Modern upgrades to the 1980's-era technology behind these limits enable three orders of magnitude or greater improvement in sensitivity. The standard cosmological model provides compelling targets at this sensitivity, spanning cosmic history from the decay of primordial density perturbations to the role of baryonic feedback in structure formation. Fully utilizing this sensitivity requires concurrent improvements in our understanding of competing astrophysical foregrounds. We outline a program using proven technologies capable of detecting the minimal predicted distortions even for worst-case foreground scenarios.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN71012
    Format: application/pdf
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  • 6
    Publication Date: 2019-11-09
    Description: Following the pioneering observations with COBE in the early 1990s, studies of the cosmic mi- crowave background (CMB) have primarily focused on temperature and polarization anisotropies. CMB spectral distortions tiny departures of the CMB energy spectrum from that of a perfect blackbody provide a second, independent probe of fundamental physics, with a reach deep into the primordial Universe. The theoretical foundation of spectral distortions has seen major advances in recent years, highlighting the immense potential of this emerging field. Spectral distortions probe a fundamental property of the Universe its thermal history thereby providing additional insight into processes within the cosmological standard model(I) (CSM) as well as new physics beyond. Spectral distortions are an important tool for understanding inflation and the nature of dark matter. They shed new light on the physics of recombination and reionization, both prominent stages in the evolution of our Universe, and furnish critical information on baryonic feedback processes, in addition to probing primordial correlation functions at scales inaccessible to other tracers. In principle the range of signals is vast: many orders of magnitude of discovery space can be explored by detailed observations of the CMB energy spectrum. Several CSM signals are predicted and provide clear experimental targets that are observable with present-day technology. Confirmation of these signals would extend the reach of the CSM by orders of magnitude in physical scale as the Universe evolves from the initial stages to its present form. Their absence would pose a huge theoretical challenge, immediately pointing to new physics. Here, we advocate for a dedicated effort to measure CMB spectral distortions at the largest angular scales (greater than approximately 1) within the ESA Voyage 2050 Program. We argue that an L-class mission with a pathfinder would allow a precise measurement of all the expected CSM distortions. With an M-class mission, the primordial distortions (created at z 〉~ 10(exp 3)) would still be detected at modest significance, while the late-time distortions will continue to be measured to high accuracy. Building on the heritage of COBE/FIRAS, a spectrometer that consists of multiple, cooled (approximately equal to 0.1 K), absolutely-calibrated Fourier Transform Spectrometers (FTS) with wide frequency coverage ( approximately equal to 10 GHz to a few x THz) and all-sky spectral sensitivity at the level of 0.1 0.5 Jy/sr would be the starting point for the M-class option. A scaled and further optimized version of this concept is being envisioned as the L-class option. Such measurements can only be done from space and would deliver hundreds of absolutely-calibrated maps of the Universe at large scales, opening numerous science opportunities for cosmology and astrophysics. This will provide independent probes of inflation, dark matter and particle physics, recombination and the energy output of our Universe from at late times, turning the long-standing spectral distortion limits of COBE/FIRAS into clear detections.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN74345
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  • 7
    Publication Date: 2019-07-13
    Description: We present a new measurement of the kinematic Sunyaev-Zel'dovich effect using data from the Atacama Cosmology Telescope (ACT) and the Baryon Oscillation Spectroscopic Survey (BOSS). Using 600 square degrees of overlapping sky area, we evaluate the mean pairwise baryon momentum associated with the positions of 50,000 bright galaxies in the BOSS DR11 Large Scale Structure catalog. A non-zero signal arises from the large-scale motions of halos containing the sample galaxies. The data fits an analytical signal model well, with the optical depth to microwave photon scattering as a free parameter determining the overall signal amplitude. We estimate the covariance matrix of the mean pairwise momentum as a function of galaxy separation, using microwave sky simulations, jackknife evaluation, and bootstrap estimates. The most conservative simulation-based errors give signal-to-noise estimates between 3.6 and 4.1 for varying galaxy luminosity cuts. We discuss how the other error determinations can lead to higher signal-to-noise values, and consider the impact of several possible systematic errors. Estimates of the optical depth from the average thermal Sunyaev-Zel'dovich signal at the sample galaxy positions are broadly consistent with those obtained from the mean pairwise momentum signal.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN41417 , Journal of Cosmology and Astroparticle Physics (ISSN 1475-7508) (e-ISSN 1475-7516); 2017; 3; 008
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