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  • 1
    ISSN: 0044-2313
    Keywords: Trifluoromethyl tellurium compounds ; crystal structure ; NMR spectra ; metathesis reactions ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of CF3TeTeCF3. Synthesis, Characterization, and Properties of CF3TeITe2(CF3)2 crystallizes in the monoclinic space group P21/a with four formular units in the unit cell. The lattice constants are a = 10.13(1) Å, b = 11.489(7) Å, c = 6.822(8) Å and β = 101.20(8)°. CF3TeI is prepared by a quantitative reaction of Te2(CF3)2 with equimolar amounts of iodine. This compound is very instable, no isolation is possible. NMR spectra have been registrated. From metathesis reactions CF3TeX (X = C≡CC6H5, t-C4H9, SCN, SC6F5) are prepared.
    Notes: Te2(CF3)2 kristallisiert in der monoklinen Raumgruppe P21/a mit vier Formeleinheiten in der Elementarzelle. Die Gitterkonstanten betragen a = 10,13(1) Å, b = 11,489(7) Å, c = 6,822(8) Å und β = 101,20(8)°. Bei der Umsetzung von Te2(CF3)2 mit der äquimolaren Menge Iod entsteht CF3TeI in quantitativer Ausbeute, eine Isolierung gelingt nicht. Die NMR-Spektren zeigen eine starke Lösungsmittelabhängigkeit. Durch Metathesereaktionen werden die Verbindungen CF3TeX (X = C≡CC6H5, t-C4H9, SCN, SC6F5) synthetisiert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2023-10-26
    Description: Ocean turbulent mixing is a key process affecting the uptake and redistribution of heat, carbon, nutrients, oxygen and other dissolved gasses. Vertical turbulent diffusivity sets the rates of water mass transformations and ocean mixing, and is intrinsically an average quantity over process time scales. Estimates based on microstructure profiling, however, are typically obtained as averages over individual profiles. How representative such averaged diffusivities are, remains unexplored in the quiescent Arctic Ocean. Here, we compare upper ocean vertical diffusivities in winter, derived from the 7Be tracer‐based approach to those estimated from direct turbulence measurements during the year‐long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, 2019–2020. We found that diffusivity estimates from both methods agree within their respective measurement uncertainties. Diffusivity estimates obtained from dissipation rate profiles are sensitive to the averaging method applied, and the processing and analysis of similar data sets must take this sensitivity into account. Our findings indicate low characteristic diffusivities around 10〈sup〉−6〈/sup〉 m〈sup〉2〈/sup〉 s〈sup〉−1〈/sup〉 and correspondingly low vertical heat fluxes.
    Description: Plain Language Summary: Ocean turbulent mixing plays an important role in the uptake and redistribution of heat, carbon, nutrients, oxygen and other properties. For example, this process delivers nutrients to the sunlit surface ocean where they are utilized to produce plants (phytoplankton) for the ecosystem food web. However, strong changes in density within the upper Arctic Ocean hinder vertical transport of nutrients, such that nutrient fluxes are generally smaller than those observed elsewhere in the world ocean. Furthermore, low vertical transport rates isolate the surface ocean from heat input from below which helps protect the ice from melting. Here, we compare the strength of upper ocean mixing, an important parameter for the calculation of vertical transport, derived from two independent methods during the MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) ice drift experiment, 2019–2020. This comparison allows us to better quantify the vertical diffusivity, and in turn also the vertical transport of for example, heat and nutrients in the ocean.
    Description: Key Points: Arctic Ocean vertical diffusivity (K〈sub〉z〈/sub〉) in the upper halocline in winter is O(10〈sup〉−6〈/sup〉) m〈sup〉2〈/sup〉 s〈sup〉−1〈/sup〉. Diffusivity estimates from 〈sup〉7〈/sup〉Be measurements and ocean microstructure profiling agree within a factor of 2. K〈sub〉z〈/sub〉 estimates from turbulent dissipation rate profiles are sensitive to the averaging method.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Research Council of Norway
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1594/PANGAEA.939816
    Description: https://doi.org/10.26008/1912/bco-dmo.861596.1
    Keywords: ddc:551.46 ; Arctic Ocean ; vertical mixing ; halocline ; winter ; turbulent diffusivity ; microstructure profiling
    Language: English
    Type: doc-type:article
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