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  • Articles  (2)
  • Arctic Ocean  (1)
  • Coral Sr/Ca ratios  (1)
  • 1
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    Interlaboratory study for coral Sr/Ca and other element/Ca ratio measurements (2013)
    John Wiley & Sons
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 14 (2013): 3730–3750, doi:10.1002/ggge.20230.
    Description: The Sr/Ca ratio of coral aragonite is used to reconstruct past sea surface temperature (SST). Twenty-one laboratories took part in an interlaboratory study of coral Sr/Ca measurements. Results show interlaboratory bias can be significant, and in the extreme case could result in a range in SST estimates of 7°C. However, most of the data fall within a narrower range and the Porites coral reference material JCp-1 is now characterized well enough to have a certified Sr/Ca value of 8.838 mmol/mol with an expanded uncertainty of 0.089 mmol/mol following International Association of Geoanalysts (IAG) guidelines. This uncertainty, at the 95% confidence level, equates to 1.5°C for SST estimates using Porites, so is approaching fitness for purpose. The comparable median within laboratory error is 〈0.5°C. This difference in uncertainties illustrates the interlaboratory bias component that should be reduced through the use of reference materials like the JCp-1. There are many potential sources contributing to biases in comparative methods but traces of Sr in Ca standards and uncertainties in reference solution composition can account for half of the combined uncertainty. Consensus values that fulfil the requirements to be certified values were also obtained for Mg/Ca in JCp-1 and for Sr/Ca and Mg/Ca ratios in the JCt-1 giant clam reference material. Reference values with variable fitness for purpose have also been obtained for Li/Ca, B/Ca, Ba/Ca, and U/Ca in both reference materials. In future, studies reporting coral element/Ca data should also report the average value obtained for a reference material such as the JCp-1.
    Description: E.C.H. (MARUM Fellowship) and T.F. were supported by the DFG-Research Center/Excellence Cluster ‘‘The Ocean in the Earth System,’’ University of Bremen. HVM was supported by an AINSE Research Fellowship.
    Description: 2014-03-23
    Keywords: Coral Sr/Ca ratios
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
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    Neodymium isotopes trace marine provenance of Arctic sea ice (2022)
    European Association of Geochemistry
    Details
    Publication Date: 2022-10-12
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Laukert, G., Peeken, I., Bauch, D., Krumpen, T., Hathorne, E. C., Werner, K., Gutjahr, M., & Frank, M. Neodymium isotopes trace marine provenance of Arctic sea ice. Geochemical Perspectives Letters, 22, (2022): 10–15, https://doi.org/10.7185/geochemlet.2220.
    Description: Radiogenic neodymium (Nd) isotopes (ɛNd) have the potential to serve as a geochemical tracer of the marine origin of Arctic sea ice. This capability results from pronounced ɛNd differences between the distinct marine and riverine sources, which feed the surface waters from which the ice forms. The first dissolved Nd isotope and rare earth element (REE) concentration data obtained from Arctic sea ice collected across the Fram Strait during RV Polarstern cruise PS85 in 2014 confirm the incorporation and preservation of the parental surface seawater ɛNd signatures despite efficient REE rejection. The large ɛNd variability between ice floes and within sea ice cores (−32 to −10) reflects changes in water mass distribution during ice growth and drift from the central Arctic Ocean to Fram Strait. In addition to the parental seawater composition, our new approach facilitates the reconstruction of the transfer of matter between the atmosphere, the sea ice and the ocean. In conjunction with satellite-derived drift trajectories, we enable a more accurate assessment of sea ice origin and spatiotemporal evolution, benefiting studies of sea ice biology, biodiversity, and biogeochemistry.
    Description: We acknowledge financial support by the German Federal Ministry of Education and Research (Grant BMBF 03F0776 and 03G0833) and the Ministry of Education and Science of the Russian Federation. GL also acknowledges financial support from the Ocean Frontier Institute through an award from the Canada First Research Excellence Fund.
    Keywords: Arctic Ocean ; Fram Strait ; Greenland ; Transpolar Drift ; Siberian Shelf ; sea ice ; snow ; seawater ; provenance tracers ; neodymium isotopes ; oxygen isotopes ; rare earth elements ; water masses ; circulation
    Repository Name: Woods Hole Open Access Server
    Type: Article
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