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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 240 (1996), S. 67-81 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Standard epoxy resins have good mechanical properties, but their prolonged low temperature curing time limits their potential use in clinical applications as well as in many industrial applications. A fast-curing epoxy-episulfide resin has been developed. The gel time of epoxy-episulfide made from EPONTrade mark of Shell Chemical Company. 828 ranges from 2 to 10 minutes by changing the ratio of the ingredients. The heat of reaction of this system is low, resulting in low cure shrinkage. Water absorption of the episulfide network is low. The epoxy-episulfide system cured with polyamide curing agent V-40 exhibits two transition temperatures, at about 85°C and 130°C, as shown in dynamic mechanical analysis data. In order to solve the long term stability problem of the above episulfides, and also the mixing problem, a lower viscosity resin, Eponex, was used to make Eponex-sulfide. Eponex-sulfide systems show promise in that they remain in a stable liquid form without epoxy. The other advantages appear to be retained.
    Additional Material: 13 Ill.
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Copolymers containing either 1,4-phenylenevinylene or 2,5-dimethoxy-1,4-phenylenevinylene units combined with 2,5-thienylenevinylene units were prepared in film form from precursor polymer films of the respective sulfonium salt polymers, which, in turn, were synthesized by the copolymerization of the respective bis(sulfonium salt) monomers. All of the copolymers could be “doped” with iodine to obtain films with high electrical conductivities and good air stability.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 194 (1993), S. 1115-1124 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(2-methoxy-1,4-phenylenevinylene) (PMVP) and copolymers containing both unsubstituted (1,4-phenylenevinylene, PV) and 2-methoxy-1,4-phenylenevinylene (MPV) units were prepared in thin films from their water-soluble sulfonium salt precursor polymers. Drawn films (L/L0 = 6) of the PMPV homopolymer could be doped with I2 vapor and FeCl3 to give conductivities of 3,2 and 4,0 ċ cm-1, respectively. The conductivity of FeCl3-doped copolymer films ranged from 100 to ca. 102 ċ cm-1 depending on the composition. The third-order nonlinear susceptibility, χ(3), for the PMPV film was investigated by degenerate four-wave mixing technique using 400 femtosecond pulses at 602 nm. A relatively large χ(3) value (7,9 ċ 10-10 esu) with a subpicosecond response was observed.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 1083-1088 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Rigid IPN foams were prepared by sequential polymerization of polyurethane and epoxy systems. Significantly higher compressive modulus and strength were observed with the IPN foams in comparison to the corresponding polyurethane rigid foams. The IPN foams show one glass transition temperature. The single Tg indicates the very small domain size in the PU-epoxy IPN's.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 2253-2258 
    ISSN: 0887-624X
    Keywords: electroluminescence ; thin film ; PPV ; light-emitting diode ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(2-(2′-ethylhexylthio)-5-methoxy-1,4-phenylenevinylene) (PMEHTPV) was synthesized in thin films via a water-soluble precursor polymer and characterized with thermogravimetric analysis (TGA), FT-IR, and elemental analysis, etc. The PMEHTPV film could be stretched up to 10 times and showed conductivity of 0.13 Scm-1 when doped with FeCl3. The 2-ethylhexylthio group resulted in blue-shifted absorption and emission compared to those of poly(2-2′-ethylhexyloxy-5-methoxy-1,4-phenylenevinylene) (MEH-PPV). The relative quantum efficiency of the device made by PMEHTPV was 20 times higher than that of MEH-PPV. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2253-2258, 1997
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 93-100 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(2-methoxy-5-methylthio-1,4-phenylene vinylene), PMTPV, and copolymers containing both unsubstituted or 2,5-dimethoxy-substituted and 2-methoxy-5-methylthio-1,4-phenylene vinylene units were prepared in thin films from their water-soluble, sulfonium salt precursor polymers. Doping of drawn and undrawn films of PMTPV with I2 vapor led to conductivities of 10-4-10-3 S cm-1, which is significantly lower than those reported for poly(2,5-dimethoxy-1,4-phenylene vinylene). Conductivity of I2-doped copolymer films ranges from 10-3-100 S cm-1 depending on composition.
    Additional Material: 3 Ill.
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  • 7
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 2107-2112 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly{oxy-4,4′-octafluorobiphenylyleneoxy-alt-[1,4-phenylenevinylene(3-trimethylsilyl-1,4-phenylene)vinylene-1,4-phenylene]} (PFSi) was synthesized and characterized to investigate its thermal, optical, electrical and xerographic properties. An LED (light emitting device) using PFSi as the light emitting layer exhibits maximum emission for blue light, but a high turn-on voltage. The origin of the low device performance was examined by investigating the photoconducting behavior. PFSi shows a high photoconductivity in the presence of electron acceptors such as 5-nitroanthranilonitrile (5NAN), and the photoconductivity of PFSi is improved by introducing charge transport materials such as triphenylamine (TPA).
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 197 (1996), S. 2393-2401 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(2,5-dipropargyloxy-1,4-phenylenevinylene) (PDPPV) and its copolymers were prepared as thin films via the organic-soluble and water-soluble precursor routes. Elimination and crosslinking reactions could be controlled by the temperature. Crosslinked PDPPV is stable up to 450°C. The conductivity values of undrawn and drawn FeCl3-doped PDPPV films are 5.0 × 10-2 and 2.0 × 10-1 Sċcm-1, respectively. The third-order nonlinear optical susceptibility, χ(3), for the PDPPV film was investigated by degenerate four-wave mixing (DFWM) technique at 602 nm wavelength, and found to be 2.3 × 10-10 esu.
    Additional Material: 5 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 198 (1997), S. 353-361 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(2-methoxy-5-trimethylsilyl-1,4-phenylenevinylene) (PMTSPV) was prepared as thin film via the water-soluble precursor route, and its electrical and optical properties were studied. The conductivity values of drawn (L/L0 = 7) and undrawn FeCl3-doped PMTSPV films were 0.1 and 0.5 · cm-1, respectively. The electroluminescence device was fabricated with PMTSPV as an emitting layer, and ITO and aluminium as hole-injection and electron-injecting electrodes, respectively. The threshold voltage of the device was about 4 V, and the emission maximum was at about 560 nm, with quantum efficiency of 2 × 10-4% (emitted photons per electron), which corresponds to yellow light emission. The χ(3) for the PMTSPV film was investigated by using the third-harmonic generation method at 1907 nm fundamental wavelength, and found to be 1.0 × 10-11 esu.
    Additional Material: 6 Ill.
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