ISSN:
1052-9306
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Dolichols, polyprenols and their phosphates have been investigated by fast atom bombardment mass spectrometry and suitable matrices and doping conditions have been developed. The molar response decreases with the molecular weight. The sensitivity is much higher for the phosphates, which are already in the ionized form, than for the parent alcohols. All derivatives give rise to pseudo-molecular ions. The polyprenols also gave rise to [M - 18 + H]+ ions and the phosphates produced fragment ions by elimination of [(C5H8)n + 2].
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/bms.1200211105
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