ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    ISSN: 1040-7685
    Keywords: Phase behavior ; supercritical fluid chromatography ; supercritical fluid extraction ; modifier ; propylene carbonate ; critical parameters ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The phase behavior (P-T-x) of propylene carbonate was studied using a variable volume view cell for the regions applicable to supercritical fluid chromatography (SFC) and extraction (SFE). Type 5 phase behavior was observed. Phase separation was shown to significantly alter retention and selectivity in the analysis of coal extracts by capillary SFC. Propylene carbonate was found to have limited use as a modifier in capillary SFC. With 5.1 mol% propylene carbonate at 60°C, a single phase is maintained only at pressures above 250 atm.Twenty-two methods used to estimate critical pressure (Pc), twenty-seven methods used to estimate critical temperature (Tc), and thirty methods used to estimate critical volume (Vc) were evaluated for various modifiers employed in supercritical fluid chromatography (SFC). None of the methods could predict Pc, Tc, or Vc to within a 5% relative error for all of the modifiers tested. However, several of the methods were successful in predicting Pc, Tc, or Vc to within 5% for select chemical classes of compounds.Four methods used to estimate the vapor-liquid critical loci of binary mixtures not only failed to accurately predict vapor-liquid separation, but failed to predict the type of phase separation occurring. None of the above methods could reliably estimate the critrical parameters of propylene carbonate or the critical parameters of the mixture.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 20 (1985), S. 115-121 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The positive ion-molecule reactions of OCS have been investigated in an ion cyclotron resonance spectrometer. A variety of reactions in OCS/hydrocarbon mixtures have been investigated for various C1—C4 hydrocarbons - alkanes, alkenes and alkynes. The formation of organosulfur ions is found in reactions in OCS/hydrocarbon (Cn) mixtures with n 〈4. Formation of organosulfur ions is observed from hydrocarbon ions reacting with OCS and [OCS]+· and S+· reacting with the hydrocarbons. The proton affinity of OCS has been determined to be 688.7±8 kJ mol-1 while that of CS2 is measured to be 712.1±8 kJ mol-1. Comparison with the proton affinity of CO2 shows that the proton affinity increases as sulfur is substituted for oxygen.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2019-07-13
    Description: Non-nuclear testing can be a valuable tool in the development of a space nuclear power system, providing system characterization data and allowing one to work through various fabrication, assembly and integration issues without the cost and time associated with a full ground nuclear test. In a non-nuclear test bed, electric heaters are used to simulate the heat from nuclear fuel. Testing with non-optimized heater elements allows one to assess thermal, heat transfer, and stress related attributes of a given system, but fails to demonstrate the dynamic response that would be present in an integrated, fueled reactor system. High fidelity thermal simulators that match both the static and the dynamic fuel pin performance that would be observed in an operating, fueled nuclear reactor can vastly increase the value of non-nuclear test results. With optimized simulators, the integration of thermal hydraulic hardware tests with simulated neutronie response provides a bridge between electrically heated testing and fueled nuclear testing, providing a better assessment of system integration issues, characterization of integrated system response times and response characteristics, and assessment of potential design improvements' at a relatively small fiscal investment. Initial conceptual thermal simulator designs are determined by simple one-dimensional analysis at a single axial location and at steady state conditions; feasible concepts are then input into a detailed three-dimensional model for comparison to expected fuel pin performance. Static and dynamic fuel pin performance for a proposed reactor design is determined using SINDA/FLUINT thermal analysis software, and comparison is made between the expected nuclear performance and the performance of conceptual thermal simulator designs. Through a series of iterative analyses, a conceptual high fidelity design can developed. Test results presented in this paper correspond to a "first cut" simulator design for a potential liquid metal (NaK) cooled reactor design that could be applied for Lunar surface power. Proposed refinements to this simulator design are also presented.
    Keywords: Nuclear Physics
    Type: Paper 2047 , American Nuclear Society Space Nuclear Conference (SNC) 2007; Jun 24, 2007 - Jun 28, 2007; Boston, MA; United States
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...