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  • Analytical Chemistry and Spectroscopy  (2)
  • Electronics and Electrical Engineering  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 10 (1977), S. 216-219 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 1H n.m.r. spectra of 3-mono-oxygenated and 3,7-dioxygenated N-acetyl-17-aza-D-homoandrost-5-enes show unequal populations of the amide rotational isomers in chloroform-d1 solution. The populations are dependent upon the orientation of the C-7 oxygen substituent but are independent of concentration. In pyridine-d5 solution the two rotameric states for each compound are almost equally populated.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 24 (1986), S. 803-808 
    ISSN: 0749-1581
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1H NMR chemical shifts of thirteen D-homo-5α-androstan-17a-ones have been determined by decoupling difference techniques. Shift changes, primarily of the H-8, H-9 and H-14 protons, produced by the introduction of hydroxy groups in the steroid have been shown to be of diagnostic importance.
    Additional Material: 1 Ill.
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  • 3
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    In:  CASI
    Publication Date: 2019-08-17
    Description: An electrode having higher power output is formed of an open mesh current collector such as expanded nickel covering an electrode film applied to a tube of beta-alumina solid electrolyte (BASE). A plurality of cross-members such as spaced, parallel loops of molybdenum metal wire surround the BASE tube. The loops are electrically connected by a bus wire. As the AMTEC cell is heated, the grid of expanded nickel expands more than the BASE tube and the surrounding loop of wire and become diffusion welded to the electrode film and to the wire loops.
    Keywords: Electronics and Electrical Engineering
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  • 4
    Publication Date: 2019-08-15
    Description: An electrode having increased output with slower degradation is formed of a film applied to a beta-alumina solid electrolyte (BASE). The film comprises a refractory first metal M.sup.1 such as a platinum group metal, suitably platinum or rhodium, capable of forming a liquid or a strong surface adsorption phase with sodium at the operating temperature of an alkali metal thermoelectric converter (AMTEC) and a second refractory metal insoluble in sodium or the NaM.sup.1 liquid phase such as a Group IVB, VB or VIB metal, suitably tungsten, molybdenum, tantalum or niobium. The liquid phase or surface film provides fast transport through the electrode while the insoluble refractory metal provides a structural matrix for the electrode during operation. A trilayer structure that is stable and not subject to deadhesion comprises a first, thin layer of tungsten, an intermediate co-deposited layer of tungsten-platinum and a thin surface layer of platinum.
    Keywords: Electronics and Electrical Engineering
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