ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The crystal structure of NaAlCl4 (a = 10.322(3) Å, b = 9.886(3) Å, c = 6.167(2) Å, Z = 4, space group P212121) was refined to final R and Rω values of 0.025 and 0.039 respectively, for 1240 reflections with I〉2σ(I). The thermal motion of the AlCl4- anion is in keeping with the TLS rigid-body analysis. Crystal and polycrystalline samples of this compound were studied by Raman scattering and an assignment of the observed bands was proposed. The Raman spectrum was compared with those of all members of alkaline (Li, Na, K, Rb, Cs) and pseudo-alkaline (NH4+, NO+) tetrachloroaluminates in the solid state.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250090113
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