Electronic Resource
Weinheim
:
Wiley-Blackwell
Berichte der deutschen chemischen Gesellschaft
123 (1990), S. 1481-1484
ISSN:
0009-2940
Keywords:
Alkylidyne complexes
;
Clusters
;
Halogen exchange reaction
;
Iron complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Nonacarbonylbis(μ3-methylidyne)triironHalogen exchange reaction in Fe3(CO)9(μ3—CF)2 (1) with BBr3 (3) yields Fe3(CO)9(μ3—CBr)2 (4), which can be converted by (C4H9)3SnH (5) into Fe3(CO)9(μ3—CH)2 (6). 6 is the parent compound of the bis(alkylidyne)triiron clusters. Selective reduction of the CBr moiety in Fe3(CO)9(μ3—CBr) (μ3—CCO2CH3) (7) results in the formation of Fe3(CO)9(μ3—CH) (μ3—CCO2CH3) (8). The structure of 8 has been elucidated by an X-ray crystalstructure determination.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230707
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