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Über neue Siliciumschichtverbindungen aus Calciumdisilicid (1990)

Hengge, Edwin ; Schiefer, D. ; Baumegger, A.

Springer

Monatshefte für Chemie 121 (1990), S. 259-266

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ISSN: 1434-4475

Keywords: Laminated structure of silicon compounds ; Alkoxypolysilanes ; Calcium disilicide

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary (SiCl)n is a high polymeric compounds with a layered structure, yielded from the layer lattice CaSi2 with ICl. New compounds were formed on the surface of these layers by action of polyvalent alcohols like ethanediol, 1,3-propanediol, 1,4-butanediol and glycerine. BET and IR measurements and the analysis show that all OH groups of the alcohols react with the Si-Cl linkage on one layer, forming a handle structure. (SiCl)n also reacts with trimethylaluminum, forming a polymeric methylsilicon Si(CH3) n .

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00808926

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